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4-（2,4-二氯苯基）-6-（1H-吲哚-3-基）-2,2'-联吡啶-5-腈

4-(2,4-Dichloro-phen-yl)-6-(1H-indol-3-yl)-2,2'-bipyridine-5-carbonitrile.

作者信息

Ramesh P, Sundaresan S S, Thirumurugan P, Perumal Paramasivan T, Ponnuswamy M N

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 8;65(Pt 5):o996-7. doi: 10.1107/S1600536809012392.

DOI:10.1107/S1600536809012392
PMID:21584031
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977688/
Abstract

The title compound, C(25)H(14)Cl(2)N(4), crystallizes with two independent mol-ecules in the asymmetric unit. The two pyridine rings are almost coplanar, making dihedral angles of 3.2 (1) and 8.6 (1)° in the two independent mol-ecules. The dichloro-phenyl and indole rings are twisted away from the bipyridine ring by 64.32 (5) and 18.46 (4)°, respectively in the first molecule and by 51.0 (1) and 27.99 (5)°, respectively in the second molecule. The crystal packing is stabilized by C-H⋯N, C-H⋯Cl, N-H⋯N and C-H⋯π inter-actions.

摘要

标题化合物C(25)H(14)Cl(2)N(4)在不对称单元中以两个独立分子结晶。两个吡啶环几乎共面，在两个独立分子中的二面角分别为3.2 (1)°和8.6 (1)°。在第一个分子中，二氯苯基和吲哚环分别相对于联吡啶环扭转64.32 (5)°和18.46 (4)°，在第二个分子中分别扭转51.0 (1)°和27.99 (5)°。晶体堆积通过C-H⋯N、C-H⋯Cl、N-H⋯N和C-H⋯π相互作用得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4f7/2977688/c8d3a606f4bb/e-65-0o996-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4f7/2977688/3eab17db2598/e-65-0o996-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4f7/2977688/c8d3a606f4bb/e-65-0o996-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4f7/2977688/3eab17db2598/e-65-0o996-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4f7/2977688/c8d3a606f4bb/e-65-0o996-fig2.jpg

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