十一羰基-1κC,2κC,3κC-[三-(2-氯乙基)亚磷酸酯-1κP]-三角-三钌(0)
Undeca-carbonyl-1κC,2κC,3κC-[tris-(2-chloro-eth-yl) phosphite-1κP]-triangulo-triruthenium(0).
作者信息
Shawkataly Omar Bin, Ghani Syed Sauban, Jothiramalingam Rajabathar, Yeap Chin Sing, Fun Hoong-Kun
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 4;66(Pt 10):m1191-2. doi: 10.1107/S1600536810033891.
In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(CO)(11)], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. In the crystal structure, the mol-ecules are linked into a one-dimensional column along [100] by inter-molecular C-H⋯O hydrogen bonds.
在标题化合物三角-三钌化合物[Ru₃(C₆H₁₂Cl₃O₃P)(CO)₁₁]中，一个赤道面羰基配体被一个单齿亚磷酸酯配体取代，在一个Ru原子上留下一个赤道面羰基配体和两个轴向羰基配体。其余两个Ru原子各自带有两个赤道面和两个轴向末端羰基配体。在晶体结构中，分子通过分子间C—H⋯O氢键沿[100]方向连接成一维柱体。
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