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氯[三（3-氟苯基）膦]金（I）

Chlorido[tris-(3-fluoro-phen-yl)phosphine]gold(I).

作者信息

Shawkataly Omar Bin, Tariq Abu, Ghani Syed Sauban, Yeap Chin Sing, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 8;66(Pt 10):m1217-8. doi: 10.1107/S1600536810034896.

DOI:10.1107/S1600536810034896
PMID:21587375
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983311/
Abstract

In the title gold complex, [AuCl(C(18)H(12)F(3)P)], the P-Au-Cl unit is nearly linear, with an angle of 178.13 (5)°. The three phosphine-substituted benzene rings make dihedral angles of 77.7 (3), 84.4 (3) and 77.4 (3)° with each other. Two of the three F atoms are disordered over two positions, with refined site occupancies of 0.591 (11):0.409 (11) and 0.730 (12):0.270 (12). In the crystal structure, mol-ecules are linked into a three-dimensional network by inter-molecular C-H⋯Cl and C-H⋯F hydrogen bonds.

摘要

在标题化合物金配合物[AuCl(C₁₈H₁₂F₃P)]中，P-Au-Cl单元近乎呈线性，夹角为178.13 (5)°。三个膦取代的苯环彼此间的二面角分别为77.7 (3)°、84.4 (3)°和77.4 (3)°。三个氟原子中的两个在两个位置上无序分布，精修后的位点占有率分别为0.591 (11):0.409 (11)和0.730 (12):0.270 (12)。在晶体结构中，分子通过分子间的C-H⋯Cl和C-H⋯F氢键连接成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3fd/2983311/6997a9388047/e-66-m1217-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3fd/2983311/8a94e540f6f9/e-66-m1217-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3fd/2983311/6997a9388047/e-66-m1217-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3fd/2983311/8a94e540f6f9/e-66-m1217-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3fd/2983311/6997a9388047/e-66-m1217-fig2.jpg

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