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链状聚[（E）-4,4'-（乙烯-1,2-二基）二吡啶鎓[[双（硫氰酸根-κN）铁（II）]-二-μ-硫氰酸根-κN:S；κS:N]]

catena-Poly[(E)-4,4'-(ethene-1,2-di-yl)dipyridinium [[bis-(thio-cyanato-κN)ferrate(II)]-di-μ-thio-cyanato-κN:S;κS:N]].

作者信息

Wöhlert Susanne, Wriedt Mario, Jess Inke, Näther Christian

机构信息

Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24098 Kiel, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 15;66(Pt 10):m1256. doi: 10.1107/S160053681003624X.

DOI:10.1107/S160053681003624X
PMID:21587404
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983361/
Abstract

In the title compound, {(C(12)H(12)N(2))[Fe(NCS)(4)]}(n), each Fe(II) cation is coordinated by four N-bonded and two S-bonded thio-cyanate anions in an octa-hedral coordination mode. The asymmetric unit consists of one Fe(II) cation, located on a center of inversion, as well as one protonated (E)-4,4'-(ethene-1,2-di-yl)dipyridinium dication and two thio-cyanate anions in general positions. The crystal structure consists of Fe-(NCS)(2)-Fe chains extending along the a axis, in which two further thio-cyanate anions are only terminally bonded via nitro-gen. Non-coordinating (E)-4,4'-(ethene-1,2-di-yl)dipyrid-inium cations are found between the chains.

摘要

在标题化合物{(C₁₂H₁₂N₂)[Fe(NCS)₄]}ₙ中，每个Fe(II)阳离子通过四个N键合和两个S键合的硫氰酸根阴离子以八面体配位模式配位。不对称单元由位于对称中心的一个Fe(II)阳离子、一个质子化的(E)-4,4'-(乙烯-1,2-二基)二吡啶鎓双阳离子以及处于一般位置的两个硫氰酸根阴离子组成。晶体结构由沿a轴延伸的Fe-(NCS)₂-Fe链组成，其中另外两个硫氰酸根阴离子仅通过氮末端键合。在这些链之间发现了非配位的(E)-4,4'-(乙烯-1,2-二基)二吡啶鎓阳离子。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9a/2983361/7ce9e0e1c6ad/e-66-m1256-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9a/2983361/ba2ad96b44a8/e-66-m1256-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9a/2983361/33f1f6e0c022/e-66-m1256-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9a/2983361/7ce9e0e1c6ad/e-66-m1256-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9a/2983361/ba2ad96b44a8/e-66-m1256-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9a/2983361/33f1f6e0c022/e-66-m1256-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9a/2983361/7ce9e0e1c6ad/e-66-m1256-fig3.jpg

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本文引用的文献

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Inorg Chem. 2009 Jul 20;48(14):6896-903. doi: 10.1021/ic9002498.
2
In situ solid state formation of copper(I) coordination polymers by thermal reduction of copper(II) precursor compounds: structure and reactivity of [Cu(NCS)2(pyrimidine)2]n.原位固态合成铜（I）配位聚合物通过热还原铜（II）前体化合物：[Cu（NCS）2（嘧啶）2]n 的结构和反应性。
Dalton Trans. 2009 Dec 14(46):10192-8. doi: 10.1039/b909838k. Epub 2009 Aug 28.
3
Coordination polymer changing its magnetic properties and colour by thermal decomposition: synthesis, structure and properties of new thiocyanato iron(II) coordination polymers based on 4,4'-bipyridine as ligand.
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Dalton Trans. 2009 Oct 14(38):7975-84. doi: 10.1039/b907645j. Epub 2009 Aug 12.
4
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
5
The Cambridge Structural Database: a quarter of a million crystal structures and rising.剑桥结构数据库：拥有二十五万个晶体结构且数量不断增加。
Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):380-8. doi: 10.1107/s0108768102003890. Epub 2002 May 29.