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Bis(2-amino-pyrimidine-κN)aqua-(nitrato-κO)(nitrato-κO,O')zinc(II).

作者信息

Gao Shan, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):m1279. doi: 10.1107/S1600536810036731.

Abstract

The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-amino-pyrimidine, [Zn(NO(3))(2)(C(4)H(5)N(3))(2)(H(2)O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the Zn(II) atom is a distorted octa-hedron. Intra-molecular N-H⋯O hydrogen bonds occur. In the crystal, adjacent adduct mol-ecules are linked by O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds into a layer motif parallel to (001).

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f04f/2983322/03b975fa76c3/e-66-m1279-fig1.jpg

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