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Poly[(μ(6)-benzene-1,3,5-tricarboxyl-ato-κO:O:O:O:O:O)tris-(N,N-dimethyl-formamide-κO)tris-(μ(3)-formato-κO:O')trimagnesium(II)].

作者信息

Yeh Chun-Ting, Liu Hsin-Kuan, Lin Chia-Jing, Lin Chia-Her

机构信息

Department of Chemistry, Chung-Yuan Christian University, Chung-Li 320, Taiwan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 25;66(Pt 10):m1289. doi: 10.1107/S1600536810035907.

DOI:10.1107/S1600536810035907
PMID:21587431
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983117/
Abstract

The title complex, Mg(3)(CHO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3), exhib-its a two-dimensional structure parallel to (001), which is built up from the Mg(II) atoms and bridging carboxyl-ate ligands (3 symmetry). The Mg(II) atom is six-coordinated by one O atom from a dimethyl-formamide mol-ecule, two O atoms from two μ(6)-benzene-1,3,5-tricarboxyl-ate ligands and three O atoms from three μ(3)-formate ligands in a distorted octa-hedral geometry.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f1d/2983117/1c2c9616bf7b/e-66-m1289-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f1d/2983117/67c128e52938/e-66-m1289-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f1d/2983117/1c2c9616bf7b/e-66-m1289-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f1d/2983117/67c128e52938/e-66-m1289-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f1d/2983117/1c2c9616bf7b/e-66-m1289-fig2.jpg

相似文献

1
Poly[(μ(6)-benzene-1,3,5-tricarboxyl-ato-κO:O:O:O:O:O)tris-(N,N-dimethyl-formamide-κO)tris-(μ(3)-formato-κO:O')trimagnesium(II)].
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 25;66(Pt 10):m1289. doi: 10.1107/S1600536810035907.
2
Poly[bis-(μ(6)-benzene-1,3,5-tricarboxyl-ato-κ(7)O(1),O(1'):O(1'):O(3):O(3'):O(5):O(5'))tetra-kis-(dimethyl-formamide-κO)trimagnesium(II)].聚[双-(μ(6)-苯-1,3,5-三羧酸根-κ(7)O(1),O(1'):O(1'):O(3):O(3'):O(5):O(5'))四-(二甲基甲酰胺-κO)三镁(II)]
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Poly[bis-(μ(4)-acetato-κO:O:O':O')bis-(μ(3)-acetato-κO:O:O)(μ(2)-acetato-κO:O')(μ(2)-acetic acid-κO:O')di-μ-aqua-copper(II)tris-odium].聚[双（μ(4)-乙酸根-κO:O:O':O'）双（μ(3)-乙酸根-κO:O:O）（μ(2)-乙酸根-κO:O'）（μ(2)-乙酸-κO:O'）双-μ-水合铜（II）三钠]
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Poly[[aqua-(μ(4)-1H-benzimidazole-5,6-dicarboxyl-ato-κN:O:O:O)(N,N-dimethyl-formamide-κO)cadmium(II)] dihydrate].聚[[水合-(μ(4)-1H-苯并咪唑-5,6-二羧酸根合-κN:O:O:O)(N,N-二甲基甲酰胺-κO)镉(II)]]二水合物
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Poly[[μ-aqua-bis-(μ-4,4'-bipyridine-κN:N')bis-(μ-3-hy-droxy-adamantane-1-carboxyl-ato-κO:O')bis-(3-hy-droxy-adamantane-1-carboxyl-ato-κO)dicobalt(II)] hepta-hydrate].聚[[μ-水合双-(μ-4,4'-联吡啶-κN:N')双-(μ-3-羟基金刚烷-1-羧基-κO:O')双-(3-羟基金刚烷-1-羧基-κO)二钴(II)]七水合物]
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引用本文的文献

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Poly[(μ6-benzene-1,3,5-tri-carboxyl-ato-κ(6) O (1):O (1'):O (3):O (3'):O (5):O (5'))tris-(N,N-di-methyl-formamide-κO)tris-(μ3-formato-κ(3) O:O:O')trizinc(II)].聚[（μ6 - 苯 - 1,3,5 - 三羧酸根合 - κ(6) O (1):O (1'):O (3):O (3'):O (5):O (5')）三（N,N - 二甲基甲酰胺 - κO）三（μ3 - 甲酸根合 - κ(3) O:O:O'）三锌（II）]
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