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μ-乙酸根-1:2κO:O'-三溴-2κBr-(5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂环十四碳-1,7-二烯-1κN)二锌(II)

μ-Actetato-1:2κO:O'-tribromido-2κBr-(5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-1,7-diene-1κN)dizinc(II).

作者信息

Li Huafeng, Shi Feifei, Rong Rong

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):m1338. doi: 10.1107/S1600536810033702.

Abstract

In the title compound, [Zn(2)Br(3)(CH(3)COO)(C(16)H(32)N(4))], one Zn(II) atom has a distorted square-planar coordination formed by the four macrocyclic N atoms with an acetate O atom in the apical position and the other Zn(II) atom has a tetra-hedral coordination environment formed by three Br atoms and one O acetate atom. The two Zn(II) atoms are linked by an acetate bridge. In the crystal, mol-ecules are linked into centrosymmetric dimers with graph-set motifs R(2) (2)(16) by an N-H⋯Br inter-action. The mol-ecular configuration is stabilized by an intra-molecular N-H⋯Br hydrogen bond.

摘要

在标题化合物[Zn₂Br₃(CH₃COO)(C₁₆H₃₂N₄)]中,一个Zn(II)原子具有由四个大环N原子形成的扭曲平面正方形配位,一个乙酸根O原子位于顶端位置;另一个Zn(II)原子具有由三个Br原子和一个乙酸根O原子形成的四面体配位环境。两个Zn(II)原子通过一个乙酸根桥相连。在晶体中,分子通过N—H⋯Br相互作用以R₂²(16)图式连接成中心对称二聚体。分子构型通过分子内N—H⋯Br氢键得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12e4/2983256/9242bdd027bc/e-66-m1338-fig1.jpg

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