2-氨基-6-(2,4-二氯苯基)-4-氧代-3,5-二苯基环己-2-烯甲腈
2-Amino-6-(2,4-dichloro-phen-yl)-4-oxo-3,5-diphenyl-cyclo-hex-2-enecarbonitrile.
作者信息
Ali A Jahubar, Athimoolam S, Bahadur S Asath, Raja V P Alex
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):o2593. doi: 10.1107/S1600536810035567.
Abstract
In the title compound, C(25)H(18)Cl(2)N(2)O, the cyclo-hexene ring has a sofa conformation. All the substituents in the cyclo-hexene ring, except the cyano group (which is axial) occupy equatorial positions. The crystal structure is stabilized through N-H⋯O hydrogen bonds, forming a chain extending along the b axis and through C-H⋯N and C-H⋯Cl inter-actions. It is remarkable that only one of the amino H atoms is involved in hydrogen bonding.
摘要
在标题化合物C₂₅H₁₈Cl₂N₂O中，环己烯环具有沙发式构象。除氰基（轴向）外，环己烯环中的所有取代基均占据赤道位置。晶体结构通过N—H⋯O氢键得以稳定，形成沿b轴延伸的链，并通过C—H⋯N和C—H⋯Cl相互作用。值得注意的是，只有一个氨基氢原子参与氢键形成。
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