Gunasekaran N, Karvembu R, Ng Seik Weng, Tiekink Edward R T
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 25;66(Pt 10):o2601. doi: 10.1107/S1600536810037177.
The title mol-ecule, C(16)H(24)N(2)OS, is twisted about the central N(H)-C bond with a C-N(H)-C-N torsion angle of -62.67 (15)°. The carbonyl group is twisted out of the plane of the benzene ring, forming a C-C-C=O torsion angle of -25.06 (17)°. In the crystal, mol-ecules related by centres of symmetry are linked by pairs of inter-molecular N-H⋯S hydrogen bonds, forming eight-membered {⋯HNCS}(2) synthons. These are further connected by weak via C-H⋯O contacts, forming a two-dimensional array in the bc plane.
标题分子C(16)H(24)N(2)OS围绕中心N(H)-C键扭转，C-N(H)-C-N扭转角为-62.67 (15)°。羰基扭转出苯环平面，形成C-C-C=O扭转角为-25.06 (17)°。在晶体中，通过对称中心相关的分子通过分子间N-H⋯S氢键对相连，形成八元{⋯HNCS}(2)合成子。这些通过弱的C-H⋯O接触进一步连接，在bc平面形成二维阵列。
