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1,1'-（对苯二甲烯）二吡啶鎓双（六氟磷酸盐）

1,1'-(p-Phenyl-enedimethyl-ene)dipyridinium bis-(hexa-fluoridophosphate).

作者信息

Abdul Rahim Munirah Sufiyah, Alias Yatimah, Ng Seik Weng

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):o2653. doi: 10.1107/S1600536810037992.

DOI:10.1107/S1600536810037992
PMID:21587624
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983422/
Abstract

The title salt, C(18)H(18)N(2) (2+)·2PF(6) (-), exists as non-inter-acting cations and anions. In the cation, the pyridine and phenyl-ene rings are aligned at 62.9 (1)°; the pyridine ring lies on a special position of m site symmetry and the phenyl-ene ring on a special position of 2/m site symmetry. The angle at the methyl-ene C atom is 112.8 (1)°. The anion lies on a special position of m site symmetry; four F atoms lie on this mirror plane.

摘要

标题盐C(18)H(18)N(2)(2+)·2PF(6)(-)以非相互作用的阳离子和阴离子形式存在。在阳离子中，吡啶环和苯环的夹角为62.9 (1)°；吡啶环位于m位点对称的特殊位置，苯环位于2/m位点对称的特殊位置。亚甲基C原子处的角度为112.8 (1)°。阴离子位于m位点对称的特殊位置；四个F原子位于该镜面平面上。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62a4/2983422/5da670e06055/e-66-o2653-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62a4/2983422/5da670e06055/e-66-o2653-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62a4/2983422/5da670e06055/e-66-o2653-fig1.jpg

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本文引用的文献

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