（2-羟基-7-甲氧基萘-1-基）（苯基）甲酮
(2-Hy-droxy-7-meth-oxy-naphthalen-1-yl)(phen-yl)methanone.
作者信息
Nagasawa Atsushi, Mitsui Ryosuke, Kato Yuichi, Okamoto Akiko, Yonezawa Noriyuki
机构信息
Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture & Technology, 2-24-16 Naka-machi, Koganei, Tokyo 184-8588, Japan.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):o2677. doi: 10.1107/S1600536810038547.
In the mol-ecule of the title compound, C(18)H(14)O(3), there is an intra-molecular O-H⋯O=C hydrogen bond between the carbonyl and hy-droxy groups on the naphthalene ring system. The angles between the C=O bond vector and the least-squares planes of the naphthalene ring system and the phenyl ring are 30.58 (6) and 42.82 (7)°, respectively, while the dihedral angle between the naphthalene ring system and the phenyl ring is 58.65 (5)°. In the crystal, mol-ecules are connected by pairs of inter-molecular O-H⋯O=C hydrogen bonds, forming centrosymmetric dimers.
在标题化合物C(18)H(14)O(3)的分子中，萘环体系上的羰基和羟基之间存在分子内O-H⋯O=C氢键。C=O键向量与萘环体系和苯环的最小二乘平面之间的夹角分别为30.58 (6)°和42.82 (7)°，而萘环体系和苯环之间的二面角为58.65 (5)°。在晶体中，分子通过分子间O-H⋯O=C氢键对相连，形成中心对称二聚体。
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