• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

（2,7-二甲氧基萘-1-基）（苯基）甲酮

(2,7-Dimeth-oxy-naphthalen-1-yl)(phen-yl)methanone.

作者信息

Kato Yuichi, Nagasawa Atsushi, Hijikata Daichi, Okamoto Akiko, Yonezawa Noriyuki

机构信息

Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture & Technology, Koganei, Tokyo 184-8588, Japan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):o2659. doi: 10.1107/S1600536810038195.

DOI:10.1107/S1600536810038195
PMID:21587630
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983196/
Abstract

The asymmetric unit of the title compound, C(19)H(16)O(3), contains three independent conformers. Each of the three conformers has essentially the same feature of non-coplanar aromatic rings whereby the aroyl group at the 1-position of the naphthalene ring is twisted in a perpendicular manner to the naphthalene ring. The dihedral angles between the benzene ring planes and the naphthalene ring systems are 75.34 (7), 86.47 (7) and 76.55 (6)° in the three conformers. The crystal structure is stabilized by inter-molecular C-H⋯O hydrogen bonds.

摘要

标题化合物C(19)H(16)O(3)的不对称单元包含三个独立的构象异构体。这三个构象异构体中的每一个都具有基本相同的非共面芳环特征，即萘环1位的芳酰基与萘环呈垂直扭曲。在这三个构象异构体中，苯环平面与萘环体系之间的二面角分别为75.34 (7)°、86.47 (7)°和76.55 (6)°。晶体结构通过分子间C-H⋯O氢键得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7785/2983196/bbc450da0c4d/e-66-o2659-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7785/2983196/3788cc2c36f4/e-66-o2659-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7785/2983196/e083ce1b79bb/e-66-o2659-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7785/2983196/303e74685a5f/e-66-o2659-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7785/2983196/bbc450da0c4d/e-66-o2659-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7785/2983196/3788cc2c36f4/e-66-o2659-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7785/2983196/e083ce1b79bb/e-66-o2659-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7785/2983196/303e74685a5f/e-66-o2659-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7785/2983196/bbc450da0c4d/e-66-o2659-fig4.jpg

相似文献

1
(2,7-Dimeth-oxy-naphthalen-1-yl)(phen-yl)methanone.（2,7-二甲氧基萘-1-基）（苯基）甲酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):o2659. doi: 10.1107/S1600536810038195.
2
{2,7-Dimeth-oxy-8-[4-(propan-2-yl-oxy)benzo-yl]naphthalen-1-yl}[4-(propan-2-yl-oxy)phen-yl]methanone.{2,7-二甲氧基-8-[4-(丙-2-基氧基)苯甲酰基]萘-1-基}[4-(丙-2-基氧基)苯基]甲酮
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):o444-5. doi: 10.1107/S1600536813004959. Epub 2013 Feb 28.
3
(5-Benzoyl-3,6-dimeth-oxy-naphthalen-2-yl)(phen-yl)methanone.（5-苯甲酰基-3,6-二甲氧基-萘-2-基）（苯基）甲酮
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1250. doi: 10.1107/S160053681101508X. Epub 2011 Apr 29.
4
(4-Chloro-phen-yl)(2,7-dimeth-oxy-8-nitro-naphthalen-1-yl)methanone.（4-氯苯基）（2,7-二甲氧基-8-硝基萘-1-基）甲酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 18;67(Pt 1):o155. doi: 10.1107/S1600536810051998.
5
[2,7-Dimeth-oxy-8-(4-propyl-benzo-yl)naphthalen-1-yl](4-propyl-phen-yl)methanone.[2,7-二甲氧基-8-(4-丙基苯甲酰基)萘-1-基](4-丙基苯基)甲酮
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2596. doi: 10.1107/S1600536812033582. Epub 2012 Jul 28.
6
1,8-Bis(4-amino-benzo-yl)-2,7-dimeth-oxy-naphthalene.1,8-双（4-氨基苯甲酰基）-2,7-二甲氧基萘
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 23;66(Pt 11):o2904-5. doi: 10.1107/S1600536810041346.
7
(8-Benzoyl-2,7-dimeth-oxy-naphthalen-1-yl)(4-phen-oxy-phen-yl)methanone.（8-苯甲酰基-2,7-二甲氧基-萘-1-基）（4-苯氧基苯基）甲酮
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):o395-6. doi: 10.1107/S1600536813004303. Epub 2013 Feb 20.
8
(2,7-Dimeth-oxy-naphthalen-1-yl)(4-phen-oxy-phen-yl)methanone.（2,7-二甲氧基萘-1-基）（4-苯氧基苯基）甲酮
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):o440. doi: 10.1107/S1600536813004820. Epub 2013 Feb 23.
9
(2,7-Dimeth-oxy-naphthalen-1-yl)(3-nitro-phen-yl)methanone.（2,7-二甲氧基-萘-1-基）（3-硝基-苯基）甲酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 30;66(Pt 11):o2972. doi: 10.1107/S1600536810042819.
10
{8-[4-(Bromo-meth-yl)benzo-yl]-2,7-dimeth-oxy-naphthalen-1-yl}[4-(bromo-meth-yl)phen-yl]methanone.{8-[4-(溴甲基)苯甲酰基]-2,7-二甲氧基萘-1-基}[4-(溴甲基)苯基]甲酮
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2119. doi: 10.1107/S1600536811029151. Epub 2011 Jul 23.

引用本文的文献

1
Crystal structure and Hirshfeld surface analysis of (2,7-di-eth-oxy-naphthalene-1,8-di-yl)bis-[(4-bromophen-yl)methanone].(2,7-二乙氧基萘-1,8-二基)双[(4-溴苯基)甲酮]的晶体结构和 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2024 Nov 22;80(Pt 12):1313-1317. doi: 10.1107/S205698902401123X. eCollection 2024 Nov 1.
2
1-[(Anthracen-9-yl)carbon-yl]-2,7-di-meth-oxy-naphthalene: a chain-like structure composed of face-to-face type dimeric mol-ecular aggregates.1-[(蒽-9-基)羰基]-2,7-二甲氧基萘：一种由面对面型二聚体分子聚集体组成的链状结构。
Acta Crystallogr E Crystallogr Commun. 2016 Nov 18;72(Pt 12):1819-1823. doi: 10.1107/S2056989016018077. eCollection 2016 Dec 1.
3

本文引用的文献

1
2-(2,7-Dimeth-oxy-1-naphtho-yl)benzoic acid.2-（2,7-二甲氧基-1-萘基）苯甲酸
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 27;66(Pt 3):o713. doi: 10.1107/S1600536810006847.
2
Methyl 4-(2,7-dimeth-oxy-1-naphtho-yl)benzoate.4-（2,7-二甲氧基-1-萘甲酰基）苯甲酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 6;66(Pt 3):o554. doi: 10.1107/S160053681000382X.
3
(2,7-Dimethoxy-naphthalene-1,8-di-yl)bis-(4-fluoro-benzo-yl)dimethanone.（2,7-二甲氧基萘-1,8-二亚基）双（4-氟苯甲酰基）二甲酮
Crystal structure of 1-(2-fluoro-benzo-yl)-2,7-di-meth-oxy-naphthalene.
1-(2-氟苯甲酰基)-2,7-二甲氧基萘的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Oct 4;70(Pt 11):278-80. doi: 10.1107/S1600536814020807. eCollection 2014 Nov 1.
4
(2,7-Di-meth-oxy-naphthalen-1-yl)(naph-thalen-1-yl)methanone.（2,7-二甲氧基萘-1-基）（萘-1-基）甲酮
Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 5;69(Pt 5):o663. doi: 10.1107/S1600536813008854. Print 2013 May 1.
5
Bis(1-benzoyl-7-meth-oxy-naphthalen-2-yl) terephthalate.对苯二甲酸双(1-苯甲酰基-7-甲氧基萘-2-基)酯
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 20;69(Pt 4):o557. doi: 10.1107/S1600536813007186. Print 2013 Apr 1.
6
(2,7-Dimeth-oxy-naphthalen-1-yl)(4-meth-oxy-phen-yl)methanone.（2,7-二甲氧基萘-1-基）（4-甲氧基苯基）甲酮
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):o363. doi: 10.1107/S1600536813003218. Epub 2013 Feb 9.
7
1-Benzoyl-naphthalene-2,7-diyl dibenzoate.1-苯甲酰基-萘-2,7-二基二苯甲酸酯。
Acta Crystallogr Sect E Struct Rep Online. 2013 Feb 1;69(Pt 2):o210. doi: 10.1107/S1600536812052026. Epub 2013 Jan 9.
8
(3,6-Dimeth-oxy-naphthalen-2-yl)(naphthalen-2-yl)methanone.（3,6-二甲氧基-萘-2-基）（萘-2-基）甲酮
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2653. doi: 10.1107/S1600536812034186. Epub 2012 Aug 8.
9
2,7-Dimeth-oxy-1-(2-naphtho-yl)naph-thalene.2,7-二甲氧基-1-(2-萘基)萘
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2595. doi: 10.1107/S1600536812033545. Epub 2012 Jul 28.
10
(2,7-Dimeth-oxy-naphthalen-1-yl)(4-fluoro-phen-yl)methanone.（2,7-二甲氧基萘-1-基）（4-氟苯基）甲酮
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1466. doi: 10.1107/S1600536811018332. Epub 2011 May 20.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):o329. doi: 10.1107/S1600536810000486.
4
1-(4-Chloro-benzo-yl)-2,7-dimethoxy-naphthalene.1-（4-氯苯甲酰基）-2,7-二甲氧基萘
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 19;64(Pt 7):o1278. doi: 10.1107/S1600536808017297.
5
1,8-Dibenzoyl-2,7-dimethoxy-naphthalene.1,8 - 二苯甲酰基 - 2,7 - 二甲氧基萘
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 4;64(Pt 5):o807. doi: 10.1107/S1600536808007009.
6
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.