双（2-氨基-3H-苯并噻唑鎓）双（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根）锰（II）六水合物
Bis(2-amino-3H-benzothia-zolium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-di-carbox-yl-ato)manganate(II) hexa-hydrate.
作者信息
Wang Na, Wen Yi-Hang, Lin Qiu-Yue, Feng Jie
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 9;66(Pt 7):m762. doi: 10.1107/S160053681002091X.
Abstract
In the crystal structure of the title salt, (C(7)H(7)N(2)S)(2)[Mn(C(8)H(8)O(5))(2)]·6H(2)O, the heterocyclic N atom of the 2-amino-benzothia-zole mol-ecule is protonated. The Mn(II) atom (site symmetry ) has a slightly distorted octa-hedral MnO(6) coordination defined by the bridging O atoms of the bicyclo-heptane unit and four carboxyl-ate O atoms of two symmetry-related and fully deprotonated ligands. The crystal packing is stabilized by N-H⋯O hydrogen bonds between the cations and anions and by O-H⋯O hydrogen bonds including the crystal water mol-ecules.
摘要
在标题盐（C₇H₇N₂S）₂[Mn（C₈H₈O₅）₂]·6H₂O的晶体结构中，2-氨基苯并噻唑分子的杂环N原子被质子化。Mn（II）原子（位点对称性）具有由双环庚烷单元的桥连O原子以及两个对称相关且完全去质子化配体的四个羧酸根O原子定义的略微扭曲的八面体MnO₆配位。晶体堆积通过阳离子和阴离子之间的N-H⋯O氢键以及包括结晶水分子在内的O-H⋯O氢键得以稳定。
相似文献
1
Bis(2-amino-3H-benzothia-zolium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-di-carbox-yl-ato)manganate(II) hexa-hydrate.双（2-氨基-3H-苯并噻唑鎓）双（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根）锰（II）六水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 9;66(Pt 7):m762. doi: 10.1107/S160053681002091X.
2
Bis(2-amino-3H-benzothia-zolium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato)cobaltate(II) hexa-hydrate.双（2-氨基-3H-苯并噻唑鎓）双（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根）钴（II）六水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 9;66(Pt 7):m763-4. doi: 10.1107/S1600536810020921.
3
Bis(2-amino-1,3-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato)cadmate hexa-hydrate.双（2-氨基-1,3-苯并噻唑-3-鎓）双（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根）镉六水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m818. doi: 10.1107/S1600536812022593. Epub 2012 May 26.
4
Bis(2-amino-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κ(3)O(2),O(3),O(7))nickelate(II) hexa-hydrate.双（2-氨基-苯并噻唑-3-鎓）双（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根-κ(3)O(2),O(3),O(7)）镍（II）六水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m683. doi: 10.1107/S1600536812017722. Epub 2012 Apr 28.
5
Bis(2-amino-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κ(3)O(2),O(3),O(7))zincate hexa-hydrate.双（2-氨基苯并噻唑-3-鎓）双（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根合-κ(3)O(2),O(3),O(7)）锌酸盐六水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m684. doi: 10.1107/S1600536812017886. Epub 2012 Apr 28.
6
catena-Poly[[diaqua-manganese(II)]-μ-7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato].链状聚[[二水合锰（II）]-μ-7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根]
Acta Crystallogr Sect E Struct Rep Online. 2010 May 29;66(Pt 6):m717. doi: 10.1107/S1600536810019021.
7
μ-Biphenyl-3,3',4,4'-tetra-carboxyl-ato-κO:O-bis-[triaqua-(2,2'-bipyridyl-κN,N')nickel(II)] hexa-hydrate.μ-联苯-3,3',4,4'-四羧酸根-κO:O-双-[三水合-(2,2'-联吡啶-κN,N')镍(II)] 六水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 25;65(Pt 5):m562-3. doi: 10.1107/S1600536809014639.
8
Tris(2-amino-1,3-thia-zole-κN)(7-oxa-bicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κO,O,O)cadmium(II) dihydrate.二水合三（2-氨基-1,3-噻唑-κN）（7-氧杂-双环-[2.2.1]庚烷-2,3-二羧酸根-κO,O,O）镉（II）
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 17;66(Pt 8):m961-2. doi: 10.1107/S1600536810027170.
9
Triaqua-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κO,O,O)cobalt(II) monohydrate.三水合-(7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根-κO,O,O)钴(II)一水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1119-20. doi: 10.1107/S1600536811028431. Epub 2011 Jul 23.
10
Tris(1H-imidazole-κN)(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κO,O,O)cobalt(II) 3.35-hydrate.三（1H-咪唑-κN）（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根-κO,O,O）钴（II）3.35水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 1;65(Pt 8):m854. doi: 10.1107/S1600536809024039.
引用本文的文献
1
Bis(2-amino-1,3-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato)cadmate hexa-hydrate.双（2-氨基-1,3-苯并噻唑-3-鎓）双（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根）镉六水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m818. doi: 10.1107/S1600536812022593. Epub 2012 May 26.
2
Bis(2-amino-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κ(3)O(2),O(3),O(7))zincate hexa-hydrate.双（2-氨基苯并噻唑-3-鎓）双（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根合-κ(3)O(2),O(3),O(7)）锌酸盐六水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m684. doi: 10.1107/S1600536812017886. Epub 2012 Apr 28.
3
Bis(2-amino-benzothia-zol-3-ium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κ(3)O(2),O(3),O(7))nickelate(II) hexa-hydrate.双（2-氨基-苯并噻唑-3-鎓）双（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根-κ(3)O(2),O(3),O(7)）镍（II）六水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m683. doi: 10.1107/S1600536812017722. Epub 2012 Apr 28.
4
Bis(2-amino-3H-benzothia-zolium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato)cobaltate(II) hexa-hydrate.双（2-氨基-3H-苯并噻唑鎓）双（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根）钴（II）六水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 9;66(Pt 7):m763-4. doi: 10.1107/S1600536810020921.
本文引用的文献
1
Bis(2-amino-3H-benzothia-zolium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato)cobaltate(II) hexa-hydrate.双（2-氨基-3H-苯并噻唑鎓）双（7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根）钴（II）六水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 9;66(Pt 7):m763-4. doi: 10.1107/S1600536810020921.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Manganese-induced neurotoxicity is differentially enhanced by glutathione depletion in astrocytoma and neuroblastoma cells.在星形细胞瘤和神经母细胞瘤细胞中，谷胱甘肽耗竭会差异性地增强锰诱导的神经毒性。
Neurochem Res. 2006 Nov;31(11):1349-57. doi: 10.1007/s11064-006-9179-7. Epub 2006 Oct 20.
4
A new antitumour substance, 7-oxabicyclo (2.2.1)-5-heptene-2,3-dicarboxylic anhydride.
Eur J Cancer Clin Oncol. 1982 Aug;18(8):785-93. doi: 10.1016/0277-5379(82)90078-5.
Zotero 插件