Wang Na, Wen Yi-Hang, Lin Qiu-Yue, Feng Jie
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 9;66(Pt 7):m762. doi: 10.1107/S160053681002091X.
In the crystal structure of the title salt, (C(7)H(7)N(2)S)(2)[Mn(C(8)H(8)O(5))(2)]·6H(2)O, the heterocyclic N atom of the 2-amino-benzothia-zole mol-ecule is protonated. The Mn(II) atom (site symmetry ) has a slightly distorted octa-hedral MnO(6) coordination defined by the bridging O atoms of the bicyclo-heptane unit and four carboxyl-ate O atoms of two symmetry-related and fully deprotonated ligands. The crystal packing is stabilized by N-H⋯O hydrogen bonds between the cations and anions and by O-H⋯O hydrogen bonds including the crystal water mol-ecules.
在标题盐（C₇H₇N₂S）₂[Mn（C₈H₈O₅）₂]·6H₂O的晶体结构中，2-氨基苯并噻唑分子的杂环N原子被质子化。Mn（II）原子（位点对称性）具有由双环庚烷单元的桥连O原子以及两个对称相关且完全去质子化配体的四个羧酸根O原子定义的略微扭曲的八面体MnO₆配位。晶体堆积通过阳离子和阴离子之间的N-H⋯O氢键以及包括结晶水分子在内的O-H⋯O氢键得以稳定。
