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双(2-氨基-3H-苯并噻唑鎓)双(7-氧杂双环-[2.2.1]庚烷-2,3-二羧酸根)钴(II)六水合物

Bis(2-amino-3H-benzothia-zolium) bis-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato)cobaltate(II) hexa-hydrate.

作者信息

Wang Na, Lin Qiu-Yue, Feng Jie, Li Shi-Kun, Zhao Jun-Jun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 9;66(Pt 7):m763-4. doi: 10.1107/S1600536810020921.

Abstract

In the crystal structure of the title salt, (C(7)H(7)N(2)S)(2)[Co(C(8)H(8)O(5))(2)]·6H(2)O, the heterocyclic N atom of the 2-amino-benzothia-zole mol-ecule is protonated. The Co(II) atom is situated on an inversion centre and exhibits a slightly distorted octa-hedral CoO(6) coordination defined by the bridging O atoms of the bicyclo-heptane unit and four carboxyl-ate O atoms of two symmetry-related and fully deprotonated ligands. The crystal packing is stabilized by N-H⋯O hydrogen bonds between the cations and anions and by O-H⋯O hydrogen bonds including the crystal water mol-ecules.

摘要

在标题盐(C₇H₇N₂S)₂[Co(C₈H₈O₅)₂]·6H₂O的晶体结构中,2-氨基苯并噻唑分子的杂环N原子被质子化。Co(II)原子位于一个对称中心上,呈现出由双环庚烷单元的桥连O原子以及两个对称相关且完全去质子化配体的四个羧酸根O原子所定义的略微扭曲的八面体CoO₆配位。晶体堆积通过阳离子和阴离子之间的N-H⋯O氢键以及包括结晶水分子在内的O-H⋯O氢键得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d553/3006894/d1ed31d1f5b0/e-66-0m763-fig1.jpg

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