Hökelek Tuncer, Süzen Yasemin, Tercan Barış, Tenlik Erdinç, Necefoğlu Hacali
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m807-8. doi: 10.1107/S1600536810022415.
The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(7)O(3))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains one half of the complex mol-ecule. Each Cu(II) atom is five-coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, two O atoms from two 4-meth-oxy-benzoate ligands, and one water mol-ecule, forming a distorted square-pyramidal geometry. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds link the mol-ecules into layers parallel to (01). π-π inter-actions, indicated by short inter-molecular distances of 3.801 (1) Å between the centroids of the benzene rings and 3.653 (1) Å between the centroids of the pyridine rings, further stabilize the structure.
中心对称双核标题化合物[Cu₂(C₈H₇O₃)₄(C₆H₆N₂O)₂(H₂O)₂]的不对称单元包含半个配合物分子。每个Cu(II)原子由一个桥连烟酰胺配体的一个N原子和另一个对称相关桥连烟酰胺配体的一个O原子、两个4-甲氧基苯甲酸酯配体的两个O原子以及一个水分子五配位,形成扭曲的四方锥几何构型。分子间的O—H⋯O和N—H⋯O氢键将分子连接成平行于(01)的层。苯环质心之间3.801 (1) Å以及吡啶环质心之间3.653 (1) Å的短分子间距离表明存在π-π相互作用,这进一步稳定了结构。