二水合硝酸双（硝酸根-κO）（5,7,12,14-四甲基-1,4,8,11-四氮杂环十四烷-6,13-二铵根-κN,N,N,N）铜（II）
Bis(nitrato-κO)(5,7,12,14-tetra-methyl-1,4,8,11-tetra-aza-cyclo-tetra-decane-6,13-diaminium-κN,N,N,N)copper(II) dinitrate tetra-hydrate.
作者信息
Liu Xiang-Yun, Chu Hong-Ying
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 23;66(Pt 7):m837. doi: 10.1107/S1600536810023342.
Abstract
In the title compound, Cu(NO(3))(2)(C(14)H(36)N(6))(2)·4H(2)O, the Cu(II) atom, lying on an inversion center, is six-coordinated in a distorted octa-hedral environment by four N atoms from a centrosymmetric 14-membered tetra-aza-cyclo-tetra-decane macrocyclic ligand and two O atoms from two nitrate anions. The supra-molecular network is consolidated by extensive O-H⋯O and N-H⋯O hydrogen-bonding inter-actions.
摘要
在标题化合物Cu(NO₃)₂(C₁₄H₃₆N₆)₂·4H₂O中，位于对称中心的Cu(II)原子在扭曲的八面体环境中通过来自中心对称的14元四氮杂环十四烷大环配体的四个N原子和来自两个硝酸根阴离子的两个O原子进行六配位。超分子网络通过广泛的O—H⋯O和N—H⋯O氢键相互作用得以巩固。
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