Suppr超能文献

N-(3-硝基苯基)马来酰胺酸

N-(3-Nitro-phen-yl)maleamic acid.

作者信息

Gowda B Thimme, Tokarčík Miroslav, Shakuntala K, Kožíšek Jozef, Fuess Hartmut

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):o1671-2. doi: 10.1107/S1600536810022245.

Abstract

In the title compound, C(10)H(8)N(2)O(5), the mol-ecule is slightly distorted from planarity. The mol-ecular structure is stabilized by two intra-molecular hydrogen bonds. The first is a short O-H⋯O hydrogen bond (H⋯O distance = 1.57 Å) within the maleamic acid unit and the second is a C-H⋯O hydrogen bond (H⋯O distance = 2.24 Å) which connects the amide group with the benzene ring. The nitro group is twisted by 6.2 (2)° out of the plane of the benzene ring. The crystal structure manifests a variety of hydrogen bonding. The packing is dominated by a strong inter-molecular N-H⋯O inter-action which links the mol-ecules into chains running along the b axis. The chains within a plane are further assembled by three additional types of inter-molecular C-H⋯O hydrogen bonds to form a sheet parallel to the (01) plane.

摘要

在标题化合物C₁₀H₈N₂O₅中,分子略微偏离平面性。分子结构通过两个分子内氢键得以稳定。第一个是马来酰胺酸单元内的短O—H⋯O氢键(H⋯O距离 = 1.57 Å),第二个是将酰胺基团与苯环相连的C—H⋯O氢键(H⋯O距离 = 2.24 Å)。硝基相对于苯环平面扭转了6.2 (2)°。晶体结构呈现出多种氢键作用。堆积主要由强的分子间N—H⋯O相互作用主导,该相互作用将分子连接成沿b轴延伸的链。平面内的链通过另外三种分子间C—H⋯O氢键进一步组装,形成平行于(01)平面的片层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/841a/3007040/d8ce6d59d1c9/e-66-o1671-fig1.jpg

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验