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(1R,3S,4R,4aS,7R,7aS,10R,12aR)-3-叠氮基-4,7,10-三甲基-1,10-环氧-全氢吡喃并[4,3-j][1,2]苯并二恶英

(1R,3S,4R,4aS,7R,7aS,10R,12aR)-3-Azido-4,7,10-trimethyl-1,10-epidioxy-per-hydropyrano[4,3-j][1,2]benzodiox-epine.

作者信息

Xie Lijun, Zhai Xin, Zuo Jian, Zhao Yanfang, Gong Ping

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 26;66(Pt 7):o1839. doi: 10.1107/S1600536810024566.

DOI:10.1107/S1600536810024566
PMID:21588040
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3006879/
Abstract

In the title compound, C(15)H(23)N(3)O(4), the six-membered pyran, cyclo-hexane and trioxane rings adopt chair, chair and boat conformations, respectively, while the seven-membered rings adopt distorted boat and very distorted chair conformations. In the crystal, adjacent mol-ecules are connected by weak C-H⋯N and C-H⋯O inter-actions.

摘要

在标题化合物C₁₅H₂₃N₃O₄中，六元吡喃环、环己烷环和三恶烷环分别采取椅式、椅式和船式构象，而七元环采取扭曲船式和非常扭曲的椅式构象。在晶体中，相邻分子通过弱的C—H⋯N和C—H⋯O相互作用相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/01b8/3006879/c1c082d6762a/e-66-o1839-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/01b8/3006879/c1c082d6762a/e-66-o1839-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/01b8/3006879/c1c082d6762a/e-66-o1839-fig1.jpg

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