Jasinski Jerry P, Guild Curtis J, Chidan Kumar C S, Yathirajan H S, Mayekar A N
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 20;66(Pt 11):o2832-3. doi: 10.1107/S1600536810037980.
The title compound, C(14)H(11)BrN(4)O(4), contains 3-bromo-phenyl and 2,4-dinitro-phenyl groups on opposite sides of a hydrazone unit and crystallizes with two mol-ecules in the asymmetric unit. The dihedral angles between the two ring systems in each mol-ecule are 2.0 (1) and 2.5 (4)°. Weak C-H⋯O hydrogen bonds and weak π-π stacking inter-actions [centroid-centroid distance = 3.7269 (14) Å] help to establish the packing. Intra-molecular N-H⋯O hydrogen bonds are also observed. On one of the rings, the Br atom is disordered over two equivalent positions of the phenyl ring [occupancy ratio 0.8734 (10):0.1266 (10).
标题化合物C(14)H(11)BrN(4)O(4)中,3-溴苯基和2,4-二硝基苯基位于腙单元的两侧,且在不对称单元中含有两个分子。每个分子中两个环系统之间的二面角分别为2.0 (1)°和2.5 (4)°。弱的C-H⋯O氢键和弱的π-π堆积相互作用[质心-质心距离 = 3.7269 (14) Å]有助于形成堆积。还观察到分子内的N-H⋯O氢键。在其中一个环上,Br原子在苯环的两个等效位置上无序排列[占有率比为0.8734 (10):0.1266 (10)]。