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聚[[六水合-(μ(2)-富马酸根-κO,O:O,O)双-(μ(3)-马来酸根-κO,O:O:O)二钐(III)]]六水合物

Poly[[hexa-aqua-(μ(2)-fumarato-κO,O:O,O)bis-(μ(3)-maleato-κO,O:O:O)disamarium(III)] hexa-hydrate].

作者信息

Li Bao, Wu Li-Xin

机构信息

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 10;66(Pt 12):m1540. doi: 10.1107/S1600536810045204.

DOI:10.1107/S1600536810045204
PMID:21589236
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3011504/
Abstract

In the title coordination polymer, {[Sm(2)(C(4)H(2)O(4))(3)(H(2)O)(6)]·6H(2)O}(n), the Sm(III) ion is nine-coordinated by four O atoms from three different maleate ligands, two O atoms from one fumarate ligand and three O atoms from three water mol-ecules. The fumarate ligand lies on an inversion center. Adjacent Sm(III) ions are bridged by the maleate and fumarate ligands, forming a layer parallel to (011). The layers are further linked by inter-molecular O-H⋯O hydrogen bonds into a three-dimensional supra-molecular network.

摘要

在标题配位聚合物{[Sm₂(C₄H₂O₄)₃(H₂O)₆]·6H₂O}ₙ中，Sm(III)离子由来自三个不同马来酸酯配体的四个O原子、来自一个富马酸酯配体的两个O原子和来自三个水分子的三个O原子九配位。富马酸酯配体位于一个对称中心上。相邻的Sm(III)离子由马来酸酯和富马酸酯配体桥连，形成平行于(011)的层。这些层通过分子间O—H⋯O氢键进一步连接成三维超分子网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b5b/3011504/19eae4365c96/e-66-m1540-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b5b/3011504/b3941d7f5aac/e-66-m1540-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b5b/3011504/19eae4365c96/e-66-m1540-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b5b/3011504/b3941d7f5aac/e-66-m1540-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b5b/3011504/19eae4365c96/e-66-m1540-fig2.jpg

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本文引用的文献

1
Structure validation in chemical crystallography.化学晶体学中的结构验证
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2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.