双[2-(吡啶-2-基)乙醇-κN,O]双(硫氰酸根-κN)镍(II)
Bis[2-(pyridin-2-yl)ethanol-κN,O]bis-(thio-cyanato-κN)nickel(II).
作者信息
Lv Lei, Qiu Xiumin, Yang Jie, Liu Shizheng, Li Dacheng
机构信息
School of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 17;66(Pt 12):m1587. doi: 10.1107/S1600536810046647.
In the title complex, [Ni(NCS)(2)(C(7)H(9)NO)(2)], the Ni(II) atom is in a distorted octa-hedral coordination environment defined by two N atoms of the two thio-cyanate ions and by the N and O atoms of the two chelating 2-(pyridin-2-yl)ethanol ligands. The complex mol-ecule is located around a crystallographic inversion center. In the crystal, mol-ecules are connected into a two-dimensional polymeric structure parallel to (100) by O-H⋯S hydrogen bonds.
在标题配合物[Ni(NCS)₂(C₇H₉NO)₂]中，Ni(II)原子处于由两个硫氰酸根离子的两个N原子以及两个螯合的2-(吡啶-2-基)乙醇配体的N和O原子所定义的扭曲八面体配位环境中。配合物分子位于一个晶体学反演中心周围。在晶体中，分子通过O—H⋯S氢键连接成平行于(100)的二维聚合结构。
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