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环四（μ-萘-1,8-二羧酸根）四（二水合（2,2'-联吡啶）锰（II））四水合物

cyclo-Tetra-kis(μ-naphthalene-1,8-dicarboxyl-ato)tetra-kis-[diaqua-(2,2'-bipyridine)-manganese(II)] tetra-hydrate.

作者信息

Chen Ling

机构信息

School of Pharmacy and Material Engineering, Jinhua College of Vocation and Technology, Jinhua, Zhejiang 321017, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 30;66(Pt 12):m1705. doi: 10.1107/S1600536810049433.

DOI:10.1107/S1600536810049433
PMID:21589355
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3011697/
Abstract

In the title centrosymmetric tetra-nuclear complex, [Mn(4)(C(12)H(6)O(4))(4)(C(10)H(8)N(2))(4)(H(2)O)(8)]·4H(2)O, two independent Mn(II) ions are coordinated in a slightly disorted octa-hedral environment by two aqua ligands, two naphthalene-1,8-dicarboxyl-ate (1,8-nap) ligands and one bis-chelating 2,2'-bipyridine (2,2'-bipy) ligand. In the crystal, mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds into chains along [100]. These chains are further linked by weak π-π inter-actions with centroid-centroid distances in the range of 3.609 (2)-3.758 (1) Å, forming a three-dimensional supra-molecular network.

摘要

在标题为中心对称四核配合物[Mn₄(C₁₂H₆O₄)₄(C₁₀H₈N₂)₄(H₂O)₈]·4H₂O中，两个独立的Mn(II)离子在略微扭曲的八面体环境中，通过两个水配体、两个萘-1,8-二羧酸根（1,8-nap）配体和一个双螯合的2,2'-联吡啶（2,2'-bipy）配体进行配位。在晶体中，分子通过分子间O-H⋯O氢键沿[100]方向连接成链。这些链通过弱的π-π相互作用进一步连接，质心-质心距离在3.609 (2)-3.758 (1) Å范围内，形成三维超分子网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f44/3011697/f31823efd692/e-66-m1705-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f44/3011697/778d0520847a/e-66-m1705-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f44/3011697/f31823efd692/e-66-m1705-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f44/3011697/778d0520847a/e-66-m1705-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f44/3011697/f31823efd692/e-66-m1705-fig2.jpg

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本文引用的文献

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