Knapp Carsten, Uzun Rabiya
Institut für Anorganische und Analytische Chemie, Albert-Ludwigs-Universität Freiburg, Albertstrasse 21, 79104 Freiburg i. Br., Germany.
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 17;66(Pt 12):o3186. doi: 10.1107/S1600536810046337.
The title compound, C(36)H(30)NP(2) (+)·Br(-)·C(2)H(3)N, crystallized from a CH(3)CN/OEt(2) solution as an acetonitrile solvate. The central P-N-P angle [142.88 (10)°] is significantly larger than in the corresponding chloride and iodide structures.
标题化合物C(36)H(30)NP(2)(+)·Br(-)·C(2)H(3)N从CH(3)CN/OEt(2)溶液中结晶形成乙腈溶剂化物。中心P-N-P角[142.88 (10)°]明显大于相应的氯化物和碘化物结构中的该角度。