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4-[(9-乙基-9H-咔唑-3-基)亚氨基甲基]苯酚

4-[(9-Ethyl-9H-carbazol-3-yl)imino-meth-yl]phenol.

作者信息

Lin Songzhu, Jia Ruokun, Gao Xiaoli, Yu Haihui, Yuan Yanlin

机构信息

Northeast China Electric Power University Personnel, Jilin 132012, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 17;66(Pt 12):o3194. doi: 10.1107/S1600536810046167.

DOI:10.1107/S1600536810046167
PMID:21589488
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3011571/
Abstract

In the title compound, C(21)H(18)N(2)O, the dihedral angle between the phenol ring and the carbazole system is 39.34 (2)°. Inter-molecular O-H⋯N hydrogen bonds and C-H⋯π and π-π inter-actions [centroid-centroid distances = 3.426 (2) and 3.768 (2) Å] stabilize the crystal structure.

摘要

在标题化合物C₂₁H₁₈N₂O中，苯酚环与咔唑体系之间的二面角为39.34 (2)°。分子间的O—H⋯N氢键以及C—H⋯π和π—π相互作用[质心-质心距离 = 3.426 (2) 和3.768 (2) Å]使晶体结构得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f976/3011571/e5efb3c64215/e-66-o3194-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f976/3011571/e5efb3c64215/e-66-o3194-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f976/3011571/e5efb3c64215/e-66-o3194-fig1.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Three polar derivatives of N-ethylcarbazole: materials for optical applications.N-乙基咔唑的三种极性衍生物：用于光学应用的材料。
Acta Crystallogr C. 2002 Feb;58(Pt 2):o72-5. doi: 10.1107/s0108270101020170. Epub 2002 Jan 16.