• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

7-氯-1,5-二炔丙基-1H-1,5-苯并二氮杂卓-2,4(3H,5H)-二酮

7-Chloro-1,5-dipropargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione.

作者信息

Dardouri Rachid, Kandri Rodi Youssef, Saffon Natalie, Essassi El Mokhtar, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 20;66(Pt 12):o3228. doi: 10.1107/S1600536810047008.

DOI:10.1107/S1600536810047008
PMID:21589518
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3011384/
Abstract

The seven-membered ring of the title compound, C(15)H(11)ClN(2)O(2), adopts a boat-shaped conformation (with the C atoms of the fused-ring as the stern and the methyl-ene C atom as the prow). The N atoms exists in a trigonal-planar coordination; one of the acetyl-enic H atoms forms a C-H⋯O hydrogen bond to the O atom of an adjacent mol-ecule, generating a linear chain along a body diagonal.

摘要

标题化合物C(15)H(11)ClN(2)O(2)的七元环呈船形构象（稠环的C原子为船尾，亚甲基C原子为船头）。N原子呈三角平面配位；其中一个乙炔基H原子与相邻分子的O原子形成C-H⋯O氢键，沿体对角线形成一条线性链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8c1/3011384/68c6b8f0aec7/e-66-o3228-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8c1/3011384/e0c3cddf6f8d/e-66-o3228-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8c1/3011384/68c6b8f0aec7/e-66-o3228-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8c1/3011384/e0c3cddf6f8d/e-66-o3228-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8c1/3011384/68c6b8f0aec7/e-66-o3228-fig2.jpg

相似文献

1
7-Chloro-1,5-dipropargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione.7-氯-1,5-二炔丙基-1H-1,5-苯并二氮杂卓-2,4(3H,5H)-二酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 20;66(Pt 12):o3228. doi: 10.1107/S1600536810047008.
2
3-{[3-(4-Meth-oxy-phen-yl)-4,5-dihydro-1,2-oxazol-5-yl]meth-yl}-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione.3-{[3-(4-甲氧基苯基)-4,5-二氢-1,2-恶唑-5-基]甲基}-1,5-二甲基-1H-1,5-苯并二氮杂卓-2,4(3H,5H)-二酮
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):o1729. doi: 10.1107/S1600536811022872. Epub 2011 Jun 18.
3
2-Hy-droxy-2,3,5,10,11,11a-hexa-hydro-1H-pyrrolo-[2,1-c][1,4]benzodiazepine-5,11-dione.2-羟基-2,3,5,10,11,11a-六氢-1H-吡咯并-[2,1-c][1,4]苯并二氮杂卓-5,11-二酮
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o1906. doi: 10.1107/S1600536811025244. Epub 2011 Jul 6.
4
1,5-Dimethyl-3-propargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione.1,5-二甲基-3-炔丙基-1H-1,5-苯并二氮杂䓬-2,4(3H,5H)-二酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 26;66(Pt 7):o1797. doi: 10.1107/S1600536810024219.
5
3-{[3-(4-Chloro-phen-yl)-4,5-dihydro-1,2-oxazol-5-yl]meth-yl}-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione.3-{[3-(4-氯苯基)-4,5-二氢-1,2-恶唑-5-基]甲基}-1,5-二甲基-1H-1,5-苯并二氮杂卓-2,4(3H,5H)-二酮
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 26;67(Pt 3):o720. doi: 10.1107/S160053681100657X.
6
3-(12-Bromo-dodec-yl)-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione.3-(12-溴十二烷基)-1,5-二甲基-1H-1,5-苯并二氮杂䓬-2,4(3H,5H)-二酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 13;66(Pt 11):o2805. doi: 10.1107/S1600536810040134.
7
3-(6-Bromo-hex-yl)-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione.3-(6-溴己基)-1,5-二甲基-1H-1,5-苯并二氮杂䓬-2,4(3H,5H)-二酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 13;66(Pt 11):o2804. doi: 10.1107/S1600536810040122.
8
1-Phenyl-3H-2,3-benzodiazepin-4(5H)-one.1-苯基-3H-2,3-苯并二氮杂䓬-4(5H)-酮
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2443. doi: 10.1107/S1600536812031327. Epub 2012 Jul 14.
9
Crystal structure of 1,5-diethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-di-thione.1,5 - 二乙基 - 1H - 1,5 - 苯并二氮杂䓬 - 2,4(3H,5H) - 二硫酮的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jan 3;71(Pt 2):o83. doi: 10.1107/S205698901402790X. eCollection 2015 Feb 1.
10
1,3,3,5-Tetra-methyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione.1,3,3,5-四甲基-1H-1,5-苯并二氮杂䓬-2,4(3H,5H)-二酮
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o783. doi: 10.1107/S1600536811007501. Epub 2011 Mar 5.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.