Yuan Jing, Cai Zhi-Qiang, Huang Chang-Jiang, Xu Wei-Ren
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 20;66(Pt 12):o3258. doi: 10.1107/S1600536810047707.
In the title compound, C(11)H(19)NO(5), the five-membered pyrrolidine ring adopts an envelope conformation. The dihedral angles between the carboxyl group plane, the pyrrolidine ring and the meth-oxy group are 59.50 (3) and 62.02 (1)°, respectively. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into chains along [100]. The absolute configuration is assigned in accord with that of (2R,4R)-1-(tert-but-oxy-carbon-yl)-4-hy-droxy-pyrrolidine-2-carb-oxy-lic acid, which was the starting material in the synthesis.
在标题化合物C(11)H(19)NO(5)中,五元吡咯烷环呈信封式构象。羧基平面、吡咯烷环和甲氧基之间的二面角分别为59.50 (3)°和62.02 (1)°。在晶体中,分子间的O-H⋯O氢键将分子沿[100]方向连接成链。绝对构型根据合成起始原料(2R,4R)-1-(叔丁氧基羰基)-4-羟基吡咯烷-2-羧酸的构型确定。