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Shape-Persistent, Truxene-Based, Nano-Sized Bisterpyridine Ruthenium(II) Complexes: Synthesis and Photophysical Properties.

作者信息

Wang Jin-Liang, Chan Yi-Tsu, Moorefield Charles N, Pei Jian, Modarelli David A, Romano Natalie C, Newkome George R

机构信息

Departments of Polymer Science and Chemistry, The University of Akron, Ohio 44325-4717, USA.

出版信息

Macromol Rapid Commun. 2010 May 12;31(9-10):850-5. doi: 10.1002/marc.200900874. Epub 2010 Mar 19.

DOI:10.1002/marc.200900874
PMID:21590978
Abstract

A new series of shape-persistent metallomacromolecules G0 and G1 as well as corresponding ligands, based on thiophene-functionalized bisterpyridine-Ru(II) with truxene moieties, as the nodes, were developed. All new compounds were fully characterized by (1) H, COSY, and (13) C NMR, as well as MALDI-TOF MS. Their photophysical properties revealed that the branched scaffold resulted in high molar absorption coefficients and broad absorption making these materials potential candidates for light-harvesting.

摘要

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