University of Ioannina, Chemistry Department, 45110 Ioannina, Greece.
Chem Commun (Camb). 2011 Jul 7;47(25):7140-2. doi: 10.1039/c0cc05547f. Epub 2011 May 25.
The assembly of Er(3+) and Y(3+) cations with trans,trans-muconic acid affords a photoreactive 3D microporous MOF that, upon UV irradiation, undergoes a cycloaddition reaction (SCSC up to 55%), with in situ formation of a strained ladderane.
铒(3+)和钇(3+)阳离子与反,反-粘康酸的组装提供了一种光反应性的 3D 微孔 MOF，在紫外光照射下，经历环加成反应（SCSC 高达 55%），同时原位形成一个应变的梯烷。
