The Skaggs Institute for Chemical Biology and Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.
Chem Commun (Camb). 2011 Jul 14;47(26):7341-3. doi: 10.1039/c1cc11354b. Epub 2011 Jun 1.
The synthesis of an azo-benzene glycoluril supergelator is reported. The control over the gel/sol state can be accomplished by irradiation and heat, but also (in a unidirectional sense) by incorporation of the glycoluril into a more stable supramolecular assembly.
报道了一种偶氮苯二醇脲超分子凝胶剂的合成。通过光照和加热可以控制凝胶/溶胶状态,也可以通过将二醇脲纳入更稳定的超分子组装体来进行(在单向意义上)。