通过多组分配位驱动自组装构建功能化金属超分子四方棱柱。
Construction of functionalized metallosupramolecular tetragonal prisms via multicomponent coordination-driven self-assembly.
机构信息
Department of Chemistry, University of Utah, 315 South 1400 East Salt Lake City, Utah 84112, USA.
出版信息
Inorg Chem. 2011 Jul 4;50(13):6107-13. doi: 10.1021/ic2002157. Epub 2011 Jun 2.
Abstract
A new approach for the construction of functionalized metallosupramolecular tetragonal prisms via multicomponent, coordination-driven, template-free self-assembly is described. The combination of tetra-(4-pyridylphenyl)ethylene, a 90° Pt(II) acceptor, and ditopic bipyridine or carboxylate ligands functionalized with hydroxyl or amine groups, hydrophobic alkyl chains, or electrochemically active ferrocene, yields a suite of seven self-assembled tetragonal prisms under mild conditions. These three-dimensional metallosupramolecules were characterized by multinuclear NMR ((31)P and (1)H) and mass spectrometry. Their shapes and sizes were established using Merck Molecular Force Field (MMFF) simulations. In addition, their approximate sizes were further supported by pulsed-field-gradient spin-echo (PGSE) NMR experiments.
摘要
通过多组分、配位驱动、无模板自组装，我们描述了一种构建功能化金属超分子四方棱柱的新方法。将四(4-吡啶基苯基)乙烯、90°Pt(II)受体与双吡啶或羧酸配体结合，这些配体带有羟基或氨基、疏水性烷基链或电化学活性的二茂铁，在温和条件下得到了一套七种自组装的四方棱柱。这些三维金属超分子通过多核 NMR((31)P 和 (1)H)和质谱进行了表征。它们的形状和大小使用默克分子力学场(MMFF)模拟进行了确定。此外，通过脉冲梯度自旋回波(PGSE)NMR 实验进一步支持了它们的近似大小。
相似文献
1
Construction of functionalized metallosupramolecular tetragonal prisms via multicomponent coordination-driven self-assembly.通过多组分配位驱动自组装构建功能化金属超分子四方棱柱。
Inorg Chem. 2011 Jul 4;50(13):6107-13. doi: 10.1021/ic2002157. Epub 2011 Jun 2.
2
A facile approach toward multicomponent supramolecular structures: selective self-assembly via charge separation.一种构建多组分超分子结构的简便方法：通过电荷分离的选择性自组装。
J Am Chem Soc. 2010 Dec 1;132(47):16873-82. doi: 10.1021/ja106251f. Epub 2010 Nov 5.
3
Metallosupramolecular tetragonal prisms via multicomponent coordination-driven template-free self-assembly.通过多组分配位驱动的无模板自组装合成金属超分子四方棱柱。
J Am Chem Soc. 2010 May 12;132(18):6282-3. doi: 10.1021/ja100889h.
4
Coordination-driven self-assembly of three-dimensional supramolecular dendrimers.基于配位作用的三维超分子树状大分子的自组装。
Inorg Chem. 2010 Jun 7;49(11):4747-9. doi: 10.1021/ic100330c.
5
Construction of hexagonal prisms of variable size via coordination-driven multicomponent self-assembly.通过配位驱动的多组分自组装构建具有可变尺寸的六棱柱。
Inorg Chem. 2010 Oct 4;49(19):8653-5. doi: 10.1021/ic1014219.
6
Ambidentate pyridyl-carboxylate ligands in the coordination-driven self-assembly of 2D Pt macrocycles: self-selection for a single isomer.双齿吡啶羧酸酯配体在二维铂大环的配位驱动自组装中的作用：单一异构体的自选择
J Am Chem Soc. 2004 Dec 22;126(50):16569-74. doi: 10.1021/ja045542l.
7
Incorporation of a flexible, pyridine-functionalized Diaza-crown ether into discrete supramolecules via coordination-driven self-assembly.通过配位驱动的自组装将柔性吡啶功能化二氮杂冠醚纳入离散超分子中。
J Org Chem. 2004 Apr 16;69(8):2910-2. doi: 10.1021/jo049883t.
8
Post-self-assembly covalent chemistry of discrete multicomponent metallosupramolecular hexagonal prisms.离散多组分金属超分子六棱柱的自组装后共价化学。
J Am Chem Soc. 2011 Jul 20;133(28):10752-5. doi: 10.1021/ja204155r. Epub 2011 Jun 23.
9
Synthesis and photophysical studies of self-assembled multicomponent supramolecular coordination prisms bearing porphyrin faces.具有卟啉面的自组装多组分超分子配位棱柱的合成及光物理研究。
Proc Natl Acad Sci U S A. 2014 Jul 1;111(26):9390-5. doi: 10.1073/pnas.1408905111. Epub 2014 Jun 16.
10
Design, synthesis, and crystallographic studies of neutral platinum-based macrocycles formed via self-assembly.通过自组装形成的中性铂基大环化合物的设计、合成及晶体学研究
J Am Chem Soc. 2004 Mar 3;126(8):2464-73. doi: 10.1021/ja039235b.
引用本文的文献
1
Assembly of Six Types of Heteroleptic PdL Cages under Kinetic Control.动力学控制下六种杂配体PdL笼的组装
J Am Chem Soc. 2023 Dec 27;145(51):28061-28074. doi: 10.1021/jacs.3c09359. Epub 2023 Dec 14.
2
Pt(ii)-coordinated tricomponent self-assemblies of tetrapyridyl porphyrin and dicarboxylate ligands: are they 3D prisms or 2D bow-ties?四吡啶基卟啉与二羧酸配体的铂（II）配位三组分自组装体：它们是三维棱柱还是二维领结？
Chem Sci. 2022 Mar 9;13(14):4070-4081. doi: 10.1039/d1sc06533e. eCollection 2022 Apr 6.
3
Synthesis and photophysical studies of self-assembled multicomponent supramolecular coordination prisms bearing porphyrin faces.具有卟啉面的自组装多组分超分子配位棱柱的合成及光物理研究。
Proc Natl Acad Sci U S A. 2014 Jul 1;111(26):9390-5. doi: 10.1073/pnas.1408905111. Epub 2014 Jun 16.
4
Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.金属有机框架与自组装超分子配位络合物：比较与对比金属有机材料的设计、合成及功能
Chem Rev. 2013 Jan 9;113(1):734-77. doi: 10.1021/cr3002824. Epub 2012 Nov 2.
5
Designed post-self-assembly structural and functional modifications of a truncated tetrahedron.设计的自组装后结构和功能修饰的截断四面体。
J Am Chem Soc. 2011 Oct 26;133(42):17045-55. doi: 10.1021/ja207217t. Epub 2011 Oct 5.
6
Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.超分子配位：有限二维和三维聚集体的自组装
Chem Rev. 2011 Nov 9;111(11):6810-918. doi: 10.1021/cr200077m. Epub 2011 Aug 24.
本文引用的文献
1
A facile approach toward multicomponent supramolecular structures: selective self-assembly via charge separation.一种构建多组分超分子结构的简便方法：通过电荷分离的选择性自组装。
J Am Chem Soc. 2010 Dec 1;132(47):16873-82. doi: 10.1021/ja106251f. Epub 2010 Nov 5.
2
From an eight-component self-sorting algorithm to a trisheterometallic scalene triangle.从八组分自分拣算法到三杂三角不等边三角形。
J Am Chem Soc. 2010 Nov 17;132(45):15933-5. doi: 10.1021/ja108419k. Epub 2010 Oct 25.
3
Construction of hexagonal prisms of variable size via coordination-driven multicomponent self-assembly.通过配位驱动的多组分自组装构建具有可变尺寸的六棱柱。
Inorg Chem. 2010 Oct 4;49(19):8653-5. doi: 10.1021/ic1014219.
4
A Pd6 molecular cage via multicomponent self-assembly incorporating both neutral and anionic linkers.通过包含中性和阴离子配体的多组分自组装合成 Pd6 分子笼。
Inorg Chem. 2010 Sep 6;49(17):7647-9. doi: 10.1021/ic101139s.
5
Combining metallasupramolecular chemistry with dynamic covalent chemistry: synthesis of large molecular cages.
Angew Chem Int Ed Engl. 2010 Jul 26;49(32):5515-8. doi: 10.1002/anie.201002748.
6
Metal-coordination-driven dynamic heteroleptic architectures.金属配位驱动的动态杂化架构。
Chem Soc Rev. 2010 May;39(5):1555-75. doi: 10.1039/b922293f. Epub 2010 Feb 15.
7
Metallosupramolecular tetragonal prisms via multicomponent coordination-driven template-free self-assembly.通过多组分配位驱动的无模板自组装合成金属超分子四方棱柱。
J Am Chem Soc. 2010 May 12;132(18):6282-3. doi: 10.1021/ja100889h.
8
Impact of assembly state on the defect tolerance of TMV-based light harvesting arrays.组装状态对基于 TMV 的光捕获阵列的缺陷容忍度的影响。
J Am Chem Soc. 2010 May 5;132(17):6068-74. doi: 10.1021/ja909566z.
9
Biologically templated photocatalytic nanostructures for sustained light-driven water oxidation.基于生物模板的光催化纳米结构用于持续的光驱动水氧化。
Nat Nanotechnol. 2010 May;5(5):340-4. doi: 10.1038/nnano.2010.57. Epub 2010 Apr 11.
10
Carbon-rich supramolecular metallacycles and metallacages.富含碳的超分子金属环和金属笼。
Tetrahedron. 2008 Dec 8;64(50):11495-11503. doi: 10.1016/j.tet.2008.08.062.
Zotero 插件