在两个配位聚合物之间的晶体结构转变过程中，坚固的 [Cu2(OOCR)4] 单元的破坏与重建。
Destruction and reconstruction of the robust [Cu2(OOCR)4] unit during crystal structure transformations between two coordination polymers.
机构信息
College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin 300387, PR China.
出版信息
Chem Commun (Camb). 2011 Jul 28;47(28):8088-90. doi: 10.1039/c1cc12184g. Epub 2011 Jun 17.
PMID:21687835
Abstract
This work first demonstrates that the robust [Cu(2)(OOCR)(4)] unit can be destroyed and reconstructed in the solid state, as observed in water-induced structural interconversion of two distinct coordination polymers with 5-bromonicotinate.
摘要
这项工作首先证明了在固态中可以破坏和重建稳定的[Cu(2)(OOCR)(4)]单元，正如在 5-溴烟酰基配体诱导的两种不同配位聚合物的结构互变中观察到的那样。
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