Schlumberger-Doll Research, Cambridge, Massachusetts 02139, USA.
Annu Rev Anal Chem (Palo Alto Calif). 2011;4:393-418. doi: 10.1146/annurev-anchem-061010-113849.
Asphaltenes, the most aromatic of the heaviest components of crude oil, are critical to all aspects of petroleum utilization, including reservoir characterization, production, transportation, refining, upgrading, paving, and coating materials. The asphaltenes, which are solid, have or impart crucial and often deleterious attributes in fluids such as high viscosity, emulsion stability, low distillate yields, and inopportune phase separation. Nevertheless, fundamental uncertainties had precluded a first-principles approach to asphaltenes until now. Recently, asphaltene science has undergone a renaissance; many basic molecular and nanocolloidal properties have been resolved and codified in the modified Yen model (also known as the Yen-Mullins model), thereby enabling predictive asphaltene science. Advances in analytical chemistry, especially mass spectrometry, enable the identification of tens of thousands of distinct chemical species in crude oils and asphaltenes. These and other powerful advances in asphaltene science fall under the banner of petroleomics, which incorporates predictive petroleum science and provides a framework for future developments.
沥青质是原油中最重的芳烃成分中最芳香的一种,对石油利用的各个方面都至关重要,包括储层描述、生产、运输、精炼、升级、铺路和涂料材料。这些固体沥青质在流体中具有或赋予了至关重要且常常有害的特性,如高粘度、乳液稳定性、低馏分收率和不合时宜的相分离。尽管如此,直到现在,基础的不确定性仍阻止了对沥青质的第一性原理方法。最近,沥青质科学经历了复兴;许多基本的分子和纳米胶体性质已经在改进的 Yen 模型(也称为 Yen-Mullins 模型)中得到解决和编纂,从而使预测沥青质科学成为可能。分析化学的进步,特别是质谱分析,使得能够鉴定原油和沥青质中数以万计的不同化学物质。这些以及其他在沥青质科学方面的强大进展都属于石油组学的范畴,它包含了可预测的石油科学,并为未来的发展提供了框架。