用于氰化物的高反应性比率荧光探针的合理设计。
Rational design of a highly reactive ratiometric fluorescent probe for cyanide.
机构信息
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, People's Republic of China.
出版信息
Org Lett. 2011 Jul 15;13(14):3730-3. doi: 10.1021/ol2013928. Epub 2011 Jun 22.
PMID:21696129
Abstract
A novel highly reactive ratiometric fluorescent cyanide probe was judiciously designed based on 2-formylacrylonitrile moiety as a new cyanide reaction site. A DFT study was conducted to rationalize the extremely high reactivity nature of the ratiometric fluorescent cyanide probe.
摘要
基于 2-甲酰基丙烯腈部分作为新的氰化物反应位点，设计了一种新型高反应性比率荧光氰化物探针。进行了 DFT 研究，以合理化比率荧光氰化物探针的极高反应性。
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