State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116012, China.
Chem Commun (Camb). 2011 Aug 7;47(29):8415-7. doi: 10.1039/c1cc11698c. Epub 2011 Jun 24.
A homochiral metal-organic triangle Co-Pro1 was achieved via self-assembly by incorporating a L-proline moiety within the corresponding ligand. Co-Pro1 comprised L-proline moieties as asymmetric catalytic active sites and a helical-like cavity, it worked as an asymmetric catalyst to prompt aldol reactions with size-, stereo- and enantioselectivity.
通过在相应配体中引入 L-脯氨酸部分，实现了手性金属有机三角形 Co-Pro1 的自组装。Co-Pro1 包含 L-脯氨酸部分作为不对称催化活性位点和螺旋状空腔，它可以作为不对称催化剂，以大小、立体和对映选择性促进醛醇反应。
