Interdisciplinary School of Green Energy/Institute of Advanced Materials and Devices, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798, South Korea.
Org Lett. 2011 Aug 5;13(15):3880-3. doi: 10.1021/ol2012378. Epub 2011 Jun 27.
Novel quinoxaline-based organic sensitizers using vertical (RC-21) and horizontal (RC-22) conjugation between an electron-donating triphenylamine unit and electron-accepting quinoxaline unit have been synthesized and used for dye-sensitized solar cells (DSSCs), leading to the relatively high power conversion efficiencies of 3.30 and 5.56% for RC-21 and RC-22, respectively. This result indicates that the quinoxaline electron-accepting unit is quite a promising candidate in organic sensitizers.
合成了基于新型喹喔啉的有机敏化剂,该敏化剂采用供电子三苯胺单元和受电子喹喔啉单元的垂直(RC-21)和水平(RC-22)共轭,用于染料敏化太阳能电池(DSSC),分别得到了 3.30%和 5.56%的相对较高的功率转换效率。这一结果表明,喹喔啉电子受体单元在有机敏化剂中是一个很有前途的候选者。