Scherf Ullrich, Adamczyk Sylwia, Gutacker Andrea, Koenen Nils
Macromolecular Chemistry Group and Institute for Polymer Technology, Bergische Universität Wuppertal, Gauss-Str. 20, D-42097 Wuppertal, Germany.
Macromol Rapid Commun. 2009 Jul 1;30(13):1059-65. doi: 10.1002/marc.200900088. Epub 2009 May 6.
Based on their rigid-rod structure all-conjugated, rod-rod block copolymers show a preferred tendency to self-assemble into low-curvature vesicular or lamellar nanostructures independent from their specific chemical structure and composition. This unique and attractive behaviour is clearly illustrated in a few examples of such all-conjugated block copolymers. The resulting nanostructured heteromaterials may find applications in electronic devices or artificial membranes.
基于其全共轭的刚性棒状结构，棒-棒嵌段共聚物显示出一种优先倾向，即自发组装成低曲率的囊泡状或层状纳米结构，而与其特定的化学结构和组成无关。这种独特且引人注目的行为在一些此类全共轭嵌段共聚物的例子中得到了清晰的体现。由此产生的纳米结构异质材料可能在电子器件或人工膜中找到应用。
