Zhang Guangzhao, Wu Chi
Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemical Physics, University of Science and Technology of China, Hefei, China.
Macromol Rapid Commun. 2009 Feb 18;30(4-5):328-35. doi: 10.1002/marc.200800611. Epub 2008 Dec 23.
The conformation of polymers at interface profoundly influences the interfacial properties. Quartz crystal microbalance with dissipation (QCM-D) is a newly developed technique to detect polymer behavior at interface in real time. In this article, we mainly review our QCM-D studies. Our focus is on temperature induced collapse and swelling of tethered polymer chains, pancake-to-brush transition and mushroom-to-brush of polymer chains.
聚合物在界面处的构象对界面性质有深远影响。带耗散监测的石英晶体微天平（QCM-D）是一种新开发的用于实时检测聚合物在界面处行为的技术。在本文中，我们主要综述我们的QCM-D研究。我们关注的是温度诱导的 tethered 聚合物链的塌缩和溶胀、聚合物链的煎饼状到刷状转变以及蘑菇状到刷状转变。 （注：“tethered”此处可能是“ tethered ”拼写有误，推测可能是“ tethered ”，意为“拴系的、束缚的” ，但因原文如此，翻译时保留原样 ）
