Jiménez Pablo, Maser Wolfgang K, Castell Pere, Martínez M Teresa, Benito Ana M
Instituto de Carboquímica (CSIC), Department of Nanotechnology, C/Miguel Luesma Castán 4, 50018 Zaragoza, Spain.
Macromol Rapid Commun. 2009 Mar 19;30(6):418-22. doi: 10.1002/marc.200800707. Epub 2009 Jan 21.
Water dispersible nanofibrilar polyaniline (NF-PANI) provides a novel and direct route towards carbon nanotube water dispersions of high concentration. Carrying out the chemical synthesis of NF-PANI in the presence of carbon nanotubes (CNTs) results in an entirely nanostructured nanofibrilar polyaniline/carbon nanotube (NF-PANI/CNT) composite material that contains well segregated CNTs partially coated by NF-PANI. This new approach is simple, fast, and inexpensive, and enables the direct preparation of stable and homogeneous dispersions of the composites in water at concentrations up to 10 mg · mL(-1) , even for the highest CNT loadings of 50 wt.-% without the participation of surfactants or stabilizers.
水分散性纳米纤维聚苯胺（NF-PANI）为制备高浓度碳纳米管水分散体提供了一条新颖且直接的途径。在碳纳米管（CNT）存在的情况下进行NF-PANI的化学合成，会得到一种完全纳米结构的纳米纤维聚苯胺/碳纳米管（NF-PANI/CNT）复合材料，其中包含被NF-PANI部分包覆且分布良好的CNT。这种新方法简单、快速且成本低廉，能够直接制备浓度高达10 mg·mL⁻¹的复合材料在水中的稳定均匀分散体，即使对于高达50 wt.-%的最高CNT负载量，也无需表面活性剂或稳定剂的参与。
