Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, Canada.
Chem Commun (Camb). 2011 Aug 14;47(30):8545-7. doi: 10.1039/c1cc12188j. Epub 2011 Jun 27.
A new tetradentate, pyridine ligand with a rigid tetrahedral core can be prepared in good yield by a cross-coupling methodology. Two metal organic framework structures of Cu(II) with PtS-type topology having a carbon atom as the tetrahedral node have been characterized utilising this ligand.
一种新的四齿配体,吡啶配体,具有刚性四面体核心,可以通过交叉偶联方法高产率制备。利用这种配体,已经对具有 PtS 拓扑结构的 Cu(II)的两种金属有机骨架结构进行了表征,其中碳原子作为四面体节点。