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甲醇衍生 ZIF-71 中乙醇和水的吸附。

Ethanol and water adsorption in methanol-derived ZIF-71.

机构信息

Algenol Biofuels, 28100 Bonita Grande Drive, Bonita Springs, FL 34315, USA.

出版信息

Chem Commun (Camb). 2011 Aug 14;47(30):8667-9. doi: 10.1039/c1cc12728d. Epub 2011 Jun 27.

DOI:10.1039/c1cc12728d
PMID:21709911
Abstract

A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions.

摘要

描述了一种在室温下合成沸石咪唑酯骨架 71(ZIF-71)的方法。基于甲醇的合成方法得到的产率>95%(基于 Zn),并且产生的晶体比先前报道的晶体具有 70%更大的表面积。ZIF 对乙醇的吸收与最近基于模型的研究相比具有优势。水的吸收明显高于模型预测。

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