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由马来酰亚胺 N-单烷基酰胺和脂肪胺形成的两亲超分子有机凝胶。

Two-component supramolecular organogels formed by maleic N-monoalkylamides and aliphatic amines.

机构信息

Key Laboratory of Jiangxi University for Materials Chemistry, Gannan Normal University, Ganzhou 341000, PR China.

出版信息

J Colloid Interface Sci. 2011 Oct 1;362(1):113-7. doi: 10.1016/j.jcis.2011.06.016. Epub 2011 Jun 13.

DOI:10.1016/j.jcis.2011.06.016
PMID:21723563
Abstract

The complexes of maleic N-monoalkylamides and aliphatic amines lead to the formation of sheet-like and fiber-shaped aggregates in diverse organic solvents. Their morphologies and microstructures were characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), as well as small angle X-ray diffraction (SA-XRD). The results reveal that the alkyl chain lengths of 8-12 carbons for maleic N-monoalkylamides, and 12-18 carbons for aliphatic amines, are suitable for obtaining highly efficient two-component gelators.

摘要

马来酸 N-单烷基酰胺与脂肪胺形成的复合物在不同有机溶剂中形成片状和纤维状聚集体。通过傅里叶变换红外光谱(FT-IR)、扫描电子显微镜(SEM)和小角 X 射线衍射(SA-XRD)对其形态和微观结构进行了表征。结果表明,马来酸 N-单烷基酰胺的烷基链长为 8-12 个碳原子,脂肪胺的烷基链长为 12-18 个碳原子,适合获得高效的双组分凝胶剂。

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