Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong, China.
Chem Commun (Camb). 2011 Aug 14;47(30):8694-6. doi: 10.1039/c1cc12446c. Epub 2011 Jul 2.
Reaction of [Ru(II)(PPh(3))(3)Cl(2)] with HQ and KCN produces a new dicyanoruthenium(III) building block, Ru(III)(Q)(2)(CN)(2). It reacts with hydrated CoCl(2) in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3.
[Ru(II)(PPh(3))(3)Cl(2)]与 HQ 和 KCN 反应生成了一种新的二氰合钌(III)建筑块,Ru(III)(Q)(2)(CN)(2)。它与水合 CoCl(2)在 MeOH 或 DMF 中反应生成三核化合物 2 或一维交错链 3。