Tekiel Antoni, Godlewski Szymon, Budzioch Janusz, Szymonski Marek
Nanotechnology. 2008 Dec 10;19(49):495304. doi: 10.1088/0957-4484/19/49/495304. Epub 2008 Nov 18.
The adsorption of 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) on a rutile TiO(2)(011)-(2 × 1) surface is studied using ultra-high vacuum scanning tunneling microscopy. The self-assembly process is dominated by the fine interplay between the lateral intermolecular interactions and the binding to the substrate. By means of temperature-induced change in the adsorption configuration and the activation of diffusion, the molecules are assembled into one-dimensional chains oriented along the [Formula: see text] crystallographic direction.
采用超高真空扫描隧道显微镜研究了3,4,9,10-苝四羧酸二酐(PTCDA)在金红石型TiO₂(011)-(2×1)表面的吸附情况。自组装过程由分子间横向相互作用与与基底的结合之间的精细相互作用主导。通过温度诱导吸附构型的变化和扩散的激活,分子组装成沿[化学式:见原文]晶体学方向排列的一维链。