Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, Assam, India.
Spectrochim Acta A Mol Biomol Spectrosc. 2011 Oct 15;81(1):313-6. doi: 10.1016/j.saa.2011.06.017. Epub 2011 Jun 22.
2,6-Bis(2-benzimidazolyl)pyridine, bbp, a simple tridentate ligand, is employed as a receptor for the recognition of anions. The binding of anionic guest species with bbp can be studied in short duration using UV/vis spectroscopy, fluorescence spectroscopy and (1)H NMR techniques at very low concentrations. The results obtained from the above spectroscopic techniques indicate that 2,6-bis(2-benzimidazolyl)pyridine is an efficient anion receptor providing chemical shift and optical modification based signals for the detection of acetate ions.
2,6-双(苯并咪唑基)吡啶(bbp)是一种简单的三齿配体,可作为阴离子识别的受体。使用紫外/可见光谱、荧光光谱和(1)H NMR 技术,可以在非常低的浓度下在短时间内研究阴离子客体与 bbp 的结合。上述光谱技术的结果表明,2,6-双(苯并咪唑基)吡啶是一种有效的阴离子受体,为检测乙酸根离子提供了基于化学位移和光学修饰的信号。