National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan.
J Am Chem Soc. 2011 Aug 10;133(31):11854-7. doi: 10.1021/ja203184k. Epub 2011 Jul 18.
In this work, with a zeolite-type metal-organic framework as both a precursor and a template and furfuryl alcohol as a second precursor, nanoporous carbon material has been prepared with an unexpectedly high surface area (3405 m(2)/g, BET method) and considerable hydrogen storage capacity (2.77 wt % at 77 K and 1 atm) as well as good electrochemical properties as an electrode material for electric double layer capacitors. The pore structure and surface area of the resultant carbon materials can be tuned simply by changing the calcination temperature.
在这项工作中，以沸石型金属有机骨架作为前体和模板，糠醇作为第二前体制备了具有高比表面积（BET 法为 3405 m(2)/g）和相当高储氢容量（77 K 和 1 大气压下为 2.77wt%）的纳米多孔碳材料，并且作为双电层电容器的电极材料还具有良好的电化学性能。通过改变煅烧温度可以简单地调节所得碳材料的孔结构和比表面积。
