• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

一种混合铟铁磷酸锂，In(0.51)Fe(0.49)LiP(2)O(7) 。

A mixed indium-iron lithium diphosphate, In(0.51)Fe(0.49)LiP(2)O(7).

作者信息

Zouihri Hafid, Saadi Mohamed, Jaber Boujemaa, El Ammari Lehcen

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):i27. doi: 10.1107/S1600536811009111. Epub 2011 Mar 15.

DOI:10.1107/S1600536811009111
PMID:21753924
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3099915/
Abstract

The structure of In(0.51)Fe(0.49)LiP(2)O(7) consists of a three-dimensional network constructed from (In(III)/Fe(III))O(6) octa-hedra and P(2)O(7) groups. Each M(III)O(6) octa-hedron is linked to six PO(4) tetra-hedra belonging to five different P(2)O(7) groups and shares two corners with the same P(2)O(7) group so as to build infinite chains or rather parallel colums of [M(III)P(2)O(11)] running along the a axis. The linkage between these chains or columns defines hepta-gonal tunnels parallel to [100] in which the Li(+) ions are located in off-centred positions. The In(0.51)Fe(0.49)LiP(2)O(7) compound can be regarded as one composition of the continuous solid solution between LiFeP(2)O(7) and LiInP(2)O(7) whose structure is isotypic with the A(I)FeP(2)O(7) (A(I) = Na, K, Rb, Cs and Ag) diphosphate family.

摘要

In(0.51)Fe(0.49)LiP(2)O(7)的结构由一个三维网络构成，该网络由(In(III)/Fe(III))O(6)八面体和P(2)O(7)基团构建而成。每个M(III)O(6)八面体与属于五个不同P(2)O(7)基团的六个PO(4)四面体相连，并与同一个P(2)O(7)基团共享两个角，从而形成沿a轴延伸的无限长链或更确切地说是平行柱体[M(III)P(2)O(11)]。这些链或柱体之间的连接定义了平行于[100]的七边形隧道，Li(+)离子位于其中的偏心位置。In(0.51)Fe(0.49)LiP(2)O(7)化合物可被视为LiFeP(2)O(7)和LiInP(2)O(7)之间连续固溶体的一种组成，其结构与A(I)FeP(2)O(7)（A(I)=Na、K、Rb、Cs和Ag）二磷酸盐家族同型。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/948d/3099915/b89ccd7f89f1/e-67-00i27-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/948d/3099915/d2e29ae6804f/e-67-00i27-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/948d/3099915/b89ccd7f89f1/e-67-00i27-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/948d/3099915/d2e29ae6804f/e-67-00i27-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/948d/3099915/b89ccd7f89f1/e-67-00i27-fig2.jpg

相似文献

1
A mixed indium-iron lithium diphosphate, In(0.51)Fe(0.49)LiP(2)O(7).一种混合铟铁磷酸锂，In(0.51)Fe(0.49)LiP(2)O(7) 。
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):i27. doi: 10.1107/S1600536811009111. Epub 2011 Mar 15.
2
Silver indium diphosphate, AgInP(2)O(7).磷酸银铟，AgInP₂O₇ 。
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 18;67(Pt 1):i2. doi: 10.1107/S1600536810052451.
3
β-Li0.37Na0.63Fe(MoO4)2.β-锂0.37钠0.63铁（钼酸）2
Acta Crystallogr Sect E Struct Rep Online. 2014 Jan 18;70(Pt 2):i9-i10. doi: 10.1107/S1600536814000646. eCollection 2014 Feb 1.
4
Dipotassium dialuminium cyclo-octa-phosphate.环八磷酸二铝二钾
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 5;66(Pt 7):i49-i50. doi: 10.1107/S1600536810020751.
5
K(2)[Fe(II) (3)(P(2)O(7))(2)(H(2)O)(2)].K(2)[Fe（II）（3）（P（2）O（7））（2）（H（2）O）（2）]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):i47-i48. doi: 10.1107/S1600536812021484. Epub 2012 May 19.
6
Disilver(I) trinickel(II) hydrogenphos-phate bis-(phosphate), Ag(2)Ni(3)(HPO(4))(PO(4))(2).
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):i40. doi: 10.1107/S1600536811021167. Epub 2011 Jun 11.
7
Na(7)Mg(13)Nd(PO(4))(12).钠（7）镁（13）钕（磷酸根）（12）
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):i44. doi: 10.1107/S1600536812017850. Epub 2012 May 16.
8
A sodium calcium arsenate, NaCa(AsO(4)).砷酸钙钠，NaCa(AsO₄) 。
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):i69. doi: 10.1107/S160053681104428X. Epub 2011 Nov 2.
9
Sodium penta-potassium penta-nickel tetra-(diphosphate), NaK(5)Ni(5)(P(2)O(7))(4).
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):i43. doi: 10.1107/S160053681202017X. Epub 2012 May 12.
10
Rb(2)Sb(4)O(11).铷锑酸盐（Rb₂Sb₄O₁₁）
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):i41. doi: 10.1107/S1600536809016109.

本文引用的文献

1
Silver indium diphosphate, AgInP(2)O(7).磷酸银铟，AgInP₂O₇ 。
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 18;67(Pt 1):i2. doi: 10.1107/S1600536810052451.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Spin dimer and classical spin analyses of the ordered magnetic structures of alkali iron pyrophosphates NaFeP(2)O(7) and LiFeP(2)O(7).碱金属焦磷酸铁盐NaFeP₂O₇和LiFeP₂O₇有序磁结构的自旋二聚体和经典自旋分析
Dalton Trans. 2004 Oct 7(19):3019-25. doi: 10.1039/b401312n. Epub 2004 Jul 23.