[4-溴-N-(吡啶-2-基亚甲基)苯胺-κN,N']双-(1,1,1,5,5,5-六氟戊烷-2,4-二酮-κO,O')镍(II)
[4-Bromo-N-(pyridin-2-yl-methyl-idene)aniline-κN,N']bis-(1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato-κO,O')nickel(II).
作者信息
Harding Phimphaka, Harding David J, Soponrat Nitisastr, Adams Harry
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m404-5. doi: 10.1107/S1600536811005599. Epub 2011 Mar 9.
Abstract
The title compound, [Ni(C(5)HF(6)O(2))(2)(C(12)H(9)BrN(2))], the Ni(II) atom exhibits a pseudo-octa-hedral coordination geometry. The structure packs through C-H⋯Br inter-actions, forming a hydrogen-bonded ladder. There are also strong hydrogen-bonding inter-actions between two of the O atoms of the β-diketonate ligands and two H atoms on the pyridine ring of the Schiff base ligand.
摘要
标题化合物[Ni(C₅HF₆O₂)₂(C₁₂H₉BrN₂)]中，Ni(II)原子呈现出一种伪八面体配位几何构型。该结构通过C-H⋯Br相互作用堆积，形成一个氢键梯子。β-二酮酸酯配体的两个O原子与席夫碱配体吡啶环上的两个H原子之间也存在强氢键相互作用。
Zotero 插件