Rizzoli Corrado, Karami Kazem, Borzooie Farzaneh
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m416-7. doi: 10.1107/S1600536811008075. Epub 2011 Mar 9.
In the cation of the title compound, [Pd(C(26)H(19)NO(3)P)(C(26)H(24)P(2))]CF(3)O(3)S·CH(2)Cl(2)·0.5C(6)H(14), the Pd(II) atom has a slightly tetra-hedrally distorted square-planar coordination geometry. The PdC(3)P and PdC(2)P(2) five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, inter-molecular C-H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dichloro-methane solvent mol-ecule is disordered over three orientations with a site-occupancy ratio of 0.5/0.3/0.2. The n-hexane solvent mol-ecule has a crystallographically imposed centre of symmetry.
在标题化合物[Pd(C₂₆H₁₉NO₃P)(C₂₆H₂₄P₂)]CF₃O₃S·CH₂Cl₂·0.5C₆H₁₄的阳离子中,Pd(II)原子具有轻微四面体畸变的平面正方形配位几何结构。PdC₃P和PdC₂P₂五元金属环分别采用信封式和扭曲构象。在晶体中,分子间C—H⋯O氢键将阳离子和阴离子连接成三维网络。二氯甲烷溶剂分子在三个取向上无序,占位比为0.5/0.3/0.2。正己烷溶剂分子具有晶体学上施加的对称中心。