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[1,2-双（二苯基膦基）乙烷-κP，P']{2-[(4-硝基苯甲酰基甲基)二苯基膦基]苯基-κC，C'}钯(II)三氟甲磺酸酯-二氯甲烷-正己烷（1/1/0.5）

[1,2-Bis(diphenyl-phosphan-yl)ethane-κP,P']{2-[(4-nitro-benzoyl-meth-yl)diphenyl-phosphan-yl]phenyl-κC,C'}palladium(II) trifluoro-methane-sulfonate-dichloro-methane-n-hexane (1/1/0.5).

作者信息

Rizzoli Corrado, Karami Kazem, Borzooie Farzaneh

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m416-7. doi: 10.1107/S1600536811008075. Epub 2011 Mar 9.

DOI:10.1107/S1600536811008075
PMID:21753947
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3099852/
Abstract

In the cation of the title compound, [Pd(C(26)H(19)NO(3)P)(C(26)H(24)P(2))]CF(3)O(3)S·CH(2)Cl(2)·0.5C(6)H(14), the Pd(II) atom has a slightly tetra-hedrally distorted square-planar coordination geometry. The PdC(3)P and PdC(2)P(2) five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, inter-molecular C-H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dichloro-methane solvent mol-ecule is disordered over three orientations with a site-occupancy ratio of 0.5/0.3/0.2. The n-hexane solvent mol-ecule has a crystallographically imposed centre of symmetry.

摘要

在标题化合物[Pd(C₂₆H₁₉NO₃P)(C₂₆H₂₄P₂)]CF₃O₃S·CH₂Cl₂·0.5C₆H₁₄的阳离子中，Pd(II)原子具有轻微四面体畸变的平面正方形配位几何结构。PdC₃P和PdC₂P₂五元金属环分别采用信封式和扭曲构象。在晶体中，分子间C—H⋯O氢键将阳离子和阴离子连接成三维网络。二氯甲烷溶剂分子在三个取向上无序，占位比为0.5/0.3/0.2。正己烷溶剂分子具有晶体学上施加的对称中心。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/708f/3099852/a17d64ea5f74/e-67-0m416-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/708f/3099852/3a5245bcf9e8/e-67-0m416-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/708f/3099852/d991a94c86de/e-67-0m416-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/708f/3099852/a17d64ea5f74/e-67-0m416-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/708f/3099852/3a5245bcf9e8/e-67-0m416-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/708f/3099852/d991a94c86de/e-67-0m416-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/708f/3099852/a17d64ea5f74/e-67-0m416-fig3.jpg

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本文引用的文献

1
Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality.钯（II）催化的C-H活化/C-C交叉偶联反应：多功能性与实用性
Angew Chem Int Ed Engl. 2009;48(28):5094-115. doi: 10.1002/anie.200806273.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Ru-, Rh-, and Pd-catalyzed C-C bond formation involving C-H activation and addition on unsaturated substrates: reactions and mechanistic aspects.
钌、铑和钯催化的涉及碳氢键活化以及在不饱和底物上加成的碳-碳键形成反应：反应及机理研究
Chem Rev. 2002 May;102(5):1731-70. doi: 10.1021/cr0104330.
4
Reactivity of Pd(0) complexes with the phosphino ylide [Ph2PCH2PPh2=C(H)C(O)Me]. Molecular structure of [Pd(PPh2CHPPh2C(H)C(O)Me)2].钯(0)配合物与膦基亚甲基叶立德[Ph2PCH2PPh2=C(H)C(O)Me]的反应活性。[Pd(PPh2CHPPh2C(H)C(O)Me)2]的分子结构。
Inorg Chem. 2000 Jun 26;39(13):2957-60. doi: 10.1021/ic990923z.