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一维有机-无机杂化物：链状聚[双-[1-(3-铵丙基)-1H-咪唑鎓][[碘化铅(II)]-三-μ-碘-铅(II)-三-μ-碘-[碘化铅(II)]-二-μ-碘]]

The one-dimensional organic-inorganic hybrid: catena-poly[bis-[1-(3-ammonio-prop-yl)-1H-imidazolium] [[iodidoplumbate(II)]-tri-μ-iodido-plumbate(II)-tri-μ-iodido-[iodidoplumbate(II)]-di-μ-iodido]].

作者信息

Trigui A, Boughzala H, Driss A, Abid Y

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m458-9. doi: 10.1107/S160053681100941X. Epub 2011 Mar 15.

DOI:10.1107/S160053681100941X
PMID:21753976
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3099864/
Abstract

The organic-inorganic hybrid, {(C(6)H(13)N(3))(2)[Pb(3)I(10)]}(n), was obtained by the reaction of 1-(3-ammonio-prop-yl)imidazolium triiodide and PbI(2) at room temperature. The structure contains one-dimensional {Pb(3)I(10)}(n) polymeric anions spreading parallel to [001], resulting from face-face-edge association of PbI(6) distorted octa-hedra. One of the Pb(II) cations is imposed at an inversion centre, whereas the second occupies a general position. N-H⋯I hydrogen bonds connect the organic cations and inorganic anions.

摘要

通过在室温下使三碘化1-(3-氨丙基)咪唑鎓与碘化铅反应，得到了有机-无机杂化物{(C₆H₁₃N₃)₂[Pb₃I₁₀]}ₙ。该结构包含一维{[Pb₃I₁₀]⁴⁻}ₙ聚合阴离子，它们平行于[001]方向伸展，由扭曲的八面体PbI₆通过面-面-边缔合形成。其中一个Pb(II)阳离子位于对称中心，而另一个占据一般位置。N-H⋯I氢键连接有机阳离子和无机阴离子。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b681/3099864/52667cdac862/e-67-0m458-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b681/3099864/66174b6b3da9/e-67-0m458-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b681/3099864/52667cdac862/e-67-0m458-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b681/3099864/66174b6b3da9/e-67-0m458-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b681/3099864/52667cdac862/e-67-0m458-fig2.jpg

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