双（乙酸根-κO,O'）[2,6-双（1H-吡唑-3-基-κN）吡啶-κN]锰（II）
Bis(acetato-κO,O')[2,6-bis-(1H-pyrazol-3-yl-κN)pyridine-κN]manganese(II).
作者信息
Yu Fan, Li Bao
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m502. doi: 10.1107/S1600536811010506. Epub 2011 Mar 26.
In the title complex, [Mn(CH(3)CO(2))(2)(C(11)H(9)N(5))], the Mn(II) atom is coordinated by the pyridine N atom and two pyrazole N atoms from a 2,6-bis-(pyrazol-3-yl)pyridine ligand and four O atoms from two bidentate acetate ligands. The complex mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds into a chain along [010]. π-π inter-actions between the pyridine rings and between the pyrazole rings [centroid-centroid distances = 3.772 (2) and 3.546 (2) Å] connect the chains.
在标题配合物[Mn(CH₃CO₂)₂(C₁₁H₉N₅)]中，Mn(II)原子由来自2,6-双(吡唑-3-基)吡啶配体的吡啶N原子和两个吡唑N原子以及来自两个双齿乙酸根配体的四个O原子配位。配合物分子通过分子间N-H⋯O氢键沿[010]方向连接成链。吡啶环之间以及吡唑环之间的π-π相互作用[质心-质心距离 = 3.772 (2) 和3.546 (2) Å]连接这些链。
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